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等级
reagent grade
质量水平
方案
≥98%
表单
powder
粒径
−325 mesh
pH值(酸碱度)
11-13 (25 °C, 138 g/L)
mp
891 °C (lit.)
SMILES字符串
[K+].[K+].[O-]C([O-])=O
InChI
1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
BWHMMNNQKKPAPP-UHFFFAOYSA-L
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一般描述
碳酸钾是一种无机碱。它作为碱参与了环钯配合物催化的氯苯与苯乙烯的 Heck 反应。
应用
碳酸钾用于以下研究:
- 多取代碘苯衍生物的合成。
- 作为合成高分子量均聚物和各种双酚衍生物的共聚物的基础。
- 作为芳基卤化物与芳基硼酸的 Suzuki 偶联的碱基。
- 作为苯乙烯和溴苯 Heck 反应的基础。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
13 - Non Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Synthesis, kinetic observations and characteristics of polyarylene ether sulphones prepared via a potassium carbonate DMAC process.
Polymer, 25(12), 1827-1836 (1984)
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Heck reaction using palladium complexed to dendrimers on silica.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)
Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids.
Journal of Organometallic Chemistry, 572(1), 141-145 (1999)
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