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Merck
CN

347825

Sigma-Aldrich

碳酸钾

reagent grade, ≥98%, powder, −325 mesh

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线性分子式:
K2CO3
CAS号:
分子量:
138.21
Beilstein:
4267587
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21

等级

reagent grade

质量水平

检测方案

≥98%

形式

powder

粒径

−325 mesh

pH值(酸碱度)

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

SMILES字符串

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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一般描述

碳酸钾是一种无机碱。它作为碱参与了环钯配合物催化的氯苯与苯乙烯的 Heck 反应。

应用

碳酸钾用于以下研究:
  • 多取代碘苯衍生物的合成。
  • 作为合成高分子量均聚物和各种双酚衍生物的共聚物的基础。
  • 作为芳基卤化物与芳基硼酸的 Suzuki 偶联的碱基。
  • 作为苯乙烯和溴苯 Heck 反应的基础。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Synthesis, kinetic observations and characteristics of polyarylene ether sulphones prepared via a potassium carbonate DMAC process.
Viswanathan R, et al.
Polymer, 25(12), 1827-1836 (1984)
Robert Möckel et al.
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Heck reaction using palladium complexed to dendrimers on silica.
Alper H, et al.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)
Carlos Arroniz et al.
Organic letters, 15(4), 910-913 (2013-02-05)
ortho-Arylation of ortho-substituted benzoic acids is a challenging process due to the tendency of the reaction products toward Pd-catalyzed protodecarboxylation. A simple method for preventing decarboxylation in sterically hindered benzoic acids is reported. The method described represents a reliable and

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