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Merck
CN

339245

Sigma-Aldrich

氢溴酸

48 wt. % in H2O, ≥99.99%

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About This Item

经验公式(希尔记法):
HBr
CAS号:
分子量:
80.91
Beilstein:
3587158
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.21

蒸汽密度

2.8 (vs air)

质量水平

蒸汽压

320 psi ( 21.1 °C)
8 mmHg ( 25 °C)

描述

48% aqueous HBr

方案

≥99.99%

表单

liquid

浓度

48 wt. % in H2O

密度

1.49 g/mL at 25 °C (lit.)

SMILES字符串

Br

InChI

1S/BrH/h1H

InChI key

CPELXLSAUQHCOX-UHFFFAOYSA-N

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一般描述

氢溴酸是一种强酸,可作为溴化试剂用于烯烃、炔烃和酮的亲电和自由基溴化。

应用

氢溴酸可作为溴化剂用于:
  • 苯并噻二唑和甲胺的溴化。
  • 烯烃、炔烃和酮氧化溴化到相对应的二溴化烷烃、烯烃和 α-溴代酮。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Masoumeh Keshavarz et al.
Advanced materials (Deerfield Beach, Fla.), 32(40), e2001878-e2001878 (2020-08-31)
Lead-free double perovskites have great potential as stable and nontoxic optoelectronic materials. Recently, Cs2 AgBiBr6 has emerged as a promising material, with suboptimal photon-to-charge carrier conversion efficiency, yet well suited for high-energy photon-detection applications. Here, the optoelectronic and structural properties
Julian A Steele et al.
ACS nano, 12(8), 8081-8090 (2018-08-08)
The room-temperature charge carrier mobility and excitation-emission properties of metal halide perovskites are governed by their electronic band structures and intrinsic lattice phonon scattering mechanisms. Establishing how charge carriers interact within this scenario will have far-reaching consequences for developing high-efficiency
Po-Yu Tsai et al.
Physical chemistry chemical physics : PCCP, 13(4), 1419-1423 (2010-11-27)
The orientation dependence of Br-atom formation in the reaction of the oriented OH radical with the HBr molecule using the hexapole electrostatic field was studied. Experimental results for the orientation dependence in the reaction were analyzed using a Legendre polynomial
Małgorzata Olejniczak et al.
The Journal of chemical physics, 136(1), 014108-014108 (2012-01-14)
We report the implementation of nuclear magnetic resonance (NMR) shielding tensors within the four-component relativistic Kohn-Sham density functional theory including non-collinear spin magnetization and employing London atomic orbitals to ensure gauge origin independent results, together with a new and efficient
Saron Catak et al.
The Journal of organic chemistry, 75(13), 4530-4541 (2010-05-29)
Ring opening of 1-arylmethyl-2-(cyanomethyl)aziridines with HBr afforded 3-(arylmethyl)amino-4-bromobutyronitriles via regiospecific ring opening at the unsubstituted aziridine carbon. Previous experimental and theoretical reports show treatment of the same compounds with benzyl bromide to furnish 4-amino-3-bromobutanenitriles through ring opening at the substituted

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