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Merck
CN

31462

Sigma-Aldrich

氯化镍(II) 六水合物

puriss. p.a., ≥98%

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About This Item

线性分子式:
NiCl2 · 6H2O
CAS号:
分子量:
237.69
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥98%
表单:
powder or crystals

等级

puriss. p.a.

质量水平

方案

≥98%

表单

powder or crystals

反应适用性

reagent type: catalyst
core: nickel

pH值(酸碱度)

4-7 (20 °C, 5%)

痕量阴离子

sulfate (SO42-): ≤50 mg/kg

痕量阳离子

Ca: ≤50 mg/kg
Cd: ≤10 mg/kg
Co: ≤100 mg/kg
Cu: ≤10 mg/kg
Fe: ≤20 mg/kg
Mg: ≤10 mg/kg
Na: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤10 mg/kg

储存温度

room temp

SMILES字符串

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ni]Cl

InChI

1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

LAIZPRYFQUWUBN-UHFFFAOYSA-L

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相关类别

一般描述

氯化镍(II)六水合物是一种水合镍盐。其晶体为单斜晶,采用X射线单晶法对其结构进行了研究。

应用

氯化镍(II)六水合物可用作四取代吡咯衍生物的高收率合成中的催化剂。它可用于将四氢吡喃基(THP)和丁基二甲基甲硅烷基(TBS)醚转化为相应的羟基化合物。

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

靶器官

Lungs

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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The Crystal Structure of Nickel Chloride Hexahydrate, NiCl2.6H2O.
Mizuno J.
Journal of the Physical Society of Japan, 16(8), 1571-1580 (1961)
A catalytic amount of nickel (II) chloride hexahydrate and 1, 2-ethanedithiol is a good combination for the cleavage of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers.
Khan AT, et al.
Tetrahedron Letters, 45(52), 9617-9621 (2004)
Synthesis of tetra-substituted pyrroles, a potential phosphodiesterase 4B inhibitor, through nickel (II) chloride hexahydrate catalyzed one-pot four-component reaction.
Khan AT, et al.
Tetrahedron Letters, 53(32), 4145-4150 (2012)
John M Besser et al.
Environmental toxicology and chemistry, 32(11), 2495-2506 (2013-05-10)
This study evaluated the chronic toxicity of Ni-spiked freshwater sediments to benthic invertebrates. A 2-step spiking procedure (spiking and sediment dilution) and a 2-stage equilibration period (10 wk anaerobic and 1 wk aerobic) were used to spike 8 freshwater sediments with wide
William G Brumbaugh et al.
Environmental toxicology and chemistry, 32(11), 2482-2494 (2013-05-10)
Two spiking methods were compared and nickel (Ni) partitioning was evaluated during a series of toxicity tests with 8 different freshwater sediments having a range of physicochemical characteristics. A 2-step spiking approach with immediate pH adjustment by addition of NaOH

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