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Merck
CN

31293

硫酸铜 五水合物

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99-102%

别名:

Cupric sulfate 五水合物, 硫酸，铜（II）盐（1：1）五水合物

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关于此项目

线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
7758-99-8
分子量:
249.69
NACRES:
NA.21
PubChem Substance ID:
329753743
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
MFCD00149681
Assay:
99-102%
Form:
solid

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产品名称

硫酸铜 五水合物, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99-102%

InChI key

JZCCFEFSEZPSOG-UHFFFAOYSA-L

InChI

1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

SMILES string

O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O

grade

ACS reagent
puriss. p.a.

agency

USP/NF
reag. ISO
reag. Ph. Eur.

vapor pressure

7.3 mmHg ( 25 °C)

assay

99-102%

form

solid

impurities

≤0.001% total nitrogen (N)
≤0.005% in water insoluble matters

pH

3.7-4.5 (20 °C, 5%)

mp

110 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg

cation traces

As: ≤0.5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤10 mg/kg
Co: ≤10 mg/kg
Fe: ≤20 mg/kg
K: ≤10 mg/kg
Mg: ≤5 mg/kg
Na: ≤20 mg/kg
Ni: ≤20 mg/kg
Pb: ≤20 mg/kg
Zn: ≤300 mg/kg

Quality Level

200

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相关类别

Application

五水硫酸铜（II）可用于以下研究：
  • 在无溶剂条件下作为醇类和酚类乙酰化的催化剂。
  • 制备用于Cu-Zn-Sn前体电沉积的电解质，它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
  • 作为乙醇的脱水反应的催化剂。

General description

五水硫酸铜（II）（CuSO4·5H2O，胆矾）是一种水合铜（II）盐。它能与三脚架配体发生水热反应，产生金属-有机骨架（MOF）。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后，它会分解成CuO。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6485
SDBB1274
SDBB0611
STBL4393
STBK7599

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Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Hangil Moon et al.
Materials (Basel, Switzerland), 13(5) (2020-03-11)
Despite the widespread application of activated carbon fiber (ACF) filters in air cleaning owing to their high surface area and low price, they have certain limitations in that they facilitate bacterial growth upon prolonged use as ACF filters can provide
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Damijana Urankar et al.
Journal of combinatorial chemistry, 10(6), 981-985 (2008-10-17)
Azoamides, previously established as bioactive intracellular GSH-depleting agents, were decorated with a terminal alkyne moiety to 4 and then were transformed, by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC), into different ligand-arm functionalized azoamides 6. Azides 5 having ligand-arms amenable for binding to
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