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等级
ACS reagent
质量水平
方案
≥99.8%
99.8-100.3% dry basis (ACS specification)
表单
crystalline powder
反应适用性
reagent type: oxidant
杂质
≤0.02% other halogens (as Cl)
pH值（酸碱度）
3.5-5.5 (25 °C, 107 g/L)
mp
300 °C (dec.) (lit.)
痕量阳离子
Mn: ≤3 ppm
储存温度
room temp
SMILES字符串
[Na+].[O-]I(=O)(=O)=O
InChI
1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
JQWHASGSAFIOCM-UHFFFAOYSA-M
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一般描述
高碘酸钠是一种无机盐，通常用作各种有机底物的氧化剂和其他一些氧化反应的助氧化剂。高碘酸钠的氧化发生在水介质中，但有机助溶剂用于不溶于水的有机基质。
应用
高碘酸钠可用作氧化剂：
- 将硫化物选择性氧化为亚砜。
- 氧化裂解各种 1,2-二醇以生成醛类或酮类。
- 将二芳基、二烷基和芳基烷基硒化物氧化为各自的硒氧化物。
- 选择性烯烃环氧化和烷烃羟基化反应。
- 选择性氧化活性纤维素，以通过裂解葡萄糖单元中 C2 – C3 之间的键得到双醛纤维素（DAC）。
- 它还可用作芳烃和卤素化合物的碘化剂。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1
靶器官
Thyroid
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
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