等级
reagent grade
质量水平
方案
≥90%
表单
powder
粒径
10 μm
mp
535 °C (dec.) (lit.)
SMILES字符串
O=[Mn]=O
InChI
1S/Mn.2O
InChI key
NUJOXMJBOLGQSY-UHFFFAOYSA-N
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一般描述
氧化锰（IV）是一种氧化试剂，可用于将丙炔醇、苯基或杂环醇、饱和醇、1,2-二醇、烯丙醇氧化为 α, β-乙烯醛或酮，并将胺氧化为醛、亚胺、酰胺和重氮化合物。它也可用于将烯丙醇转化成 α, β乙烯酯或酰胺，将腈水转化成酰胺，也可用于脱氢和芳构化反应。
应用
- 高氧化态3d金属配合物：探讨了高氧化态配合物中氧化锰(IV)对高级有机合成的催化性能，证明了其在加速化学反应和提高产率方面的关键作用，有利于制药和化学工业（Cheng J et al., 2018）。
- 锰配合物的合成与性质：详细介绍了具有独特氧化还原性质的新型锰配合物的合成，有助于了解各种化学和环境背景下的电子转移过程（Baffert C et al., 2002）。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation
靶器官
Brain
储存分类代码
13 - Non Combustible Solids
WGK
WGK 2
闪点(°F)
does not flash
闪点(°C)
does not flash
Manganese dioxide
Cahiez G, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Y Wang et al.
Journal of colloid and interface science, 380(1), 8-15 (2012-06-02)
Bio-inspired chemical approach has been developed for the surface modification and electrophoretic deposition of manganese dioxide and zirconia nanoparticles, prepared by chemical precipitation methods. Caffeic acid, trans-cinnamic acid, p-coumaric acid, and 2,4-dihydroxycinnamic acid were investigated for the surface modification of
Wen-Hui Kuan et al.
Journal of hazardous materials, 239-240, 152-159 (2012-09-25)
This study examined the reaction of methylene blue (MB) with tunneled manganese oxide pyrolusite regarding pH and reaction time. MB was cleaved through N-demethylation, in which reaction azure B (AB), azure A (AA), azure C (AC), and thionin (TH) were
Michael K L Chu et al.
Lab on a chip, 12(14), 2533-2539 (2012-05-09)
We have developed glucose-responsive implantable microdevices for closed-loop delivery of insulin and conducted in vivo testing of these devices in diabetic rats. The microdevices consist of an albumin-based bioinorganic membrane that utilizes glucose oxidase (GOx), catalase (CAT) and manganese dioxide
Highly stretchable alkaline batteries based on an embedded conductive fabric.
Abhinav M Gaikwad et al.
Advanced materials (Deerfield Beach, Fla.), 24(37), 5071-5076 (2012-07-05)
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