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关于此项目
线性分子式:
C6H5CN
化学文摘社编号:
分子量:
103.12
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39031505
UNSPSC Code:
12190000
EC Number:
202-855-7
MDL number:
Beilstein/REAXYS Number:
506893
Assay:
99.9%
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Bp:
191 °C (lit.)
SMILES string
N#Cc1ccccc1
InChI key
JFDZBHWFFUWGJE-UHFFFAOYSA-N
InChI
1S/C7H5N/c8-6-7-4-2-1-3-5-7/h1-5H
grade
HPLC grade
assay
99.9%
form
liquid
purified by
glass distillation
expl. lim.
0.34-6.3 %
technique(s)
HPLC: suitable
impurities
≤0.03% water
evapn. residue
<0.0005%
refractive index
n20/D 1.528 (lit.)
bp
191 °C (lit.)
mp
−13 °C (lit.)
λ
H2O reference
UV absorption
λ: 300 nm Amax: 1.0, λ: 310 nm Amax: 0.40, λ: 335 nm Amax: 0.03, λ: 360-400 nm Amax: 0.01
application(s)
food and beverages
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
法规信息
危险化学品
此项目有
Benzonitrile and acetonitrile complexes of ruthenium ammines.
Clarke RE and Ford PC.
Inorganic Chemistry, 9(2), 227-235 (1970)
Microwave spectra of isotopic benzonitriles. Refined molecular structure of benzonitrile.
Casado J, et al.
Journal of Molecular Structure, 8(1-2), 211-224 (1971)
Lanthanide-imido complexes and their reactions with benzonitrile.
Dongmei Cui et al.
Angewandte Chemie (International ed. in English), 44(6), 959-962 (2004-12-22)
A multiphase reaction medium including pressurized carbon dioxide and water for selective hydrogenation of benzonitrile with a Pd/Al2O3 catalyst.
Yoshida H, et al.
Applied Catalysis A: General, 456, 215-222 (2013)
Yoshimitsu Hashimoto et al.
Organic & biomolecular chemistry, 10(30), 6003-6009 (2012-05-19)
A variety of highly functionalized polycyclic isoxazoles are prepared by a two-step protocol: (1) 1,3-dipolar cycloaddition of o,o'-disubstituted benzonitrile oxides to para-quinone mono-acetals, then (2) dehydrogenation. The cycloaddition proceeds in a regioselective manner, favouring the formation of the 4-acyl cycloadducts
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