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Merck
CN

259705

Sigma-Aldrich

甲酸甲酯

spectrophotometric grade, ≥98%

别名:

蚁酸甲酯

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About This Item

线性分子式:
HCO2CH3
CAS号:
分子量:
60.05
Beilstein:
1734623
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.21

等级

spectrophotometric grade

质量水平

蒸汽密度

2.1 (vs air)

蒸汽压

32.81 psi ( 55 °C)
9.21 psi ( 20 °C)

检测方案

≥98%

形式

liquid

自燃温度

842 °F

expl. lim.

23 %

技术

UV/Vis spectroscopy: suitable

杂质

<0.010% water

蒸发残留物

<0.0005%

折射率

n20/D 1.343 (lit.)

pH值(酸碱度)

4.0-5.0 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

λ

H2O reference

紫外吸收

λ: 259 nm Amax: 1.00
λ: 260 nm Amax: 0.70
λ: 265 nm Amax: 0.20
λ: 270 nm Amax: 0.04
λ: 310-400 nm Amax: 0.01

SMILES字符串

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

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一般描述

Methyl formate (MF) is one of the most significant intermediates in C1 chemistry. MF has been used to produce methanamide, N, N-dimethylformamide, dimethyl carbonate, methyl glycolate, acetic acid, ethylene glycol, methyl methacrylate, and high-purity CO. Additionally, MF can be used as a solvent for nitrocellulose and cellulose acetate.

应用


  • Bifunctionality of Re Supported on TiO(2) in Driving Methanol Formation in Low-Temperature CO(2) Hydrogenation.: This article explores the catalytic roles of methyl formate in methanol production from CO2 hydrogenation, providing a pathway for sustainable chemical synthesis (Urakawa A et al., 2023).

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-2.2 °F - closed cup

闪点(°C)

-19 °C - closed cup

法规信息

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Barriers to rotation adjacent to double bonds. 3. The carbon-oxygen barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance.
Wiberg KB and Laidig KE.
Journal of the American Chemical Society, 109(20), 5935-5943 (1987)
Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.
Yalfani MS, et al.
ChemSusChem, 8(3), 443-447 (2015)
Microwave spectrum, barrier to internal rotation, and structure of methyl formate.
Curl Jr RF.
J. Chem. Phys. , 30(6), 1529-1536 (1959)
Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate.
Wu C, et al.
Green Chemistry, 17(3), 1467-1472 (2015)
Katherine R Phillips et al.
Journal of the American Chemical Society, 135(2), 574-577 (2012-12-28)
Methyl formate is produced from the photo-oxidation of methanol on preoxidized TiO(2)(110). We demonstrate that two consecutive photo-oxidation steps lead to methyl formate using mass spectrometry and scanning tunneling microscopy. The first step in methanol oxidation is formation of methoxy

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