249882
三氯化铝 溶液
1.0 M in nitrobenzene
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关于此项目
经验公式（希尔记法）:
AlCl3
化学文摘社编号:
分子量:
133.34
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
liquid
产品名称
三氯化铝 溶液, 1.0 M in nitrobenzene
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
SMILES string
Cl[Al](Cl)Cl
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
form
liquid
reaction suitability
reagent type: catalyst
core: aluminum
concentration
0.95-1.10 M (EDTA titration)
1.0 M in nitrobenzene
density
1.249 g/mL at 25 °C
Quality Level
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - STOT RE 1 Inhalation
target_organs
Blood
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
190.4 °F - closed cup
flash_point_c
88 °C - closed cup
法规信息
危险化学品
此项目有
Acceleration of the Diels-Alder reaction by aluminum chloride.
Yates P and Eaton P.
Journal of the American Chemical Society, 82(16), 4426-4437 (1960)
Zhiliang Huang et al.
Organic & biomolecular chemistry, 11(11), 1810-1814 (2013-02-08)
AlCl(3) promoted Friedel-Crafts acylation between 4-tert-butylbenzoyl chloride and mesitylene was investigated. The donor-acceptor complex was observed as the major species. Kinetic investigation demonstrated that the reaction was first-order on the donor-acceptor complex and zero-order on ArH, suggesting that the donor-acceptor
Amination of< i> exo</i>-2-chloronorbornane and norbornane with trichloramine-aluminum chloride.
Kovacic P, et al.
Tetrahedron, 26(2), 529-538 (1970)
Dharmalingam Prakash et al.
Neuromolecular medicine, 15(1), 192-208 (2013-01-15)
Aluminum (Al) is an environmental neurotoxin that affects cerebral functions and causes health complications. However, the role of Al in arbitrating glia homeostasis and pathophysiology remains obscure. Astrocyte, microglia activation (reactive gliosis), and associated inflammatory events play a decisive role
Bagineni Prasad et al.
Chemical communications (Cambridge, England), 48(84), 10434-10436 (2012-09-20)
A conceptually new and straightforward introduction of sulfonyl groups at the C-7 position of an indole ring has been achieved via AlCl(3) mediated unexpected regioselective sulfonyl group migration for N-alkyl/aryl/heteroarylsulfonyl indoles affording potential inhibitors of Mycobacterium tuberculosis H37Rv chorismate mutase.
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