蒸汽压
24.09 psi ( 55 °C)
6.93 psi ( 20 °C)
质量水平
表单
liquid
反应适用性
reagent type: catalyst
core: titanium
浓度
0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride
密度
1.365 g/mL at 25 °C
SMILES字符串
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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一般描述
氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。使用 pH 值为 2.5 至 6.0 的 TiCl 4 中性溶液(通过添加氧化镁作为基础制备)合成纳米二氧化钛。
应用
通过改良的 Bouveault 反应活化吡咯烷,以改善转化为相应的 α-二甲胺。
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
此项目有
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Yang Chen et al.
ChemSusChem, 4(10), 1498-1503 (2011-09-29)
Mesoporous TiO₂ beads with diameters of 320±50, 550±50, and 830±40 nm, comprising interconnected and densely packed TiO₂ nanocrystals, were used as working electrodes for dye-sensitized solar cells (DSCs). These electrodes possess high surface areas and superior light-scattering properties, which are ideal
Bratindranath Mukherjee et al.
Nanoscale, 5(1), 269-274 (2012-11-20)
The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
Kazuhiko Akiyama et al.
Journal of the American Chemical Society, 134(23), 9762-9767 (2012-05-18)
Rapid and efficient separation/purification of pure metallofullerenes M(x)@C(n) (M = metal; x = 1, 2; n > 70) and carbide metallofullerenes of the type M(y)C(2)@C(n-2) (y = 2, 3, 4; n - 2 > 68) has been reported. The present
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