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Merck
CN

248614

过硫酸铵

ACS reagent, ≥98.0%

别名:

AP, APS, PER, 过硫酸铵

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关于此项目

线性分子式:
(NH4)2S2O8
化学文摘社编号:
分子量:
228.20
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
231-786-5
MDL number:
Assay:
≥98.0%
Grade:
ACS reagent
Form:
chunks or granules
powder or crystals
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产品名称

过硫酸铵, ACS reagent, ≥98.0%

InChI key

ROOXNKNUYICQNP-UHFFFAOYSA-N

InChI

1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)

SMILES string

N.N.OS(=O)(=O)OOS(O)(=O)=O

grade

ACS reagent

vapor density

7.9 (vs air)

assay

≥98.0%

form

chunks or granules
powder or crystals

reaction suitability

reagent type: oxidant

impurities

≤0.005% insolubles
≤0.04 meq/g Titr. acid

ign. residue

≤0.05%

pH

1-2 (25 °C, 228 g/L)

anion traces

Cl- and ClO4-: ≤0.001%

cation traces

Fe: ≤0.001%
Mn: ≤0.5 ppm
heavy metals (as Pb): ≤0.005%

Quality Level

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Application

过硫酸铵可用作氧化剂,用于以下物质的无溶剂氧化:
  • 伯醇和仲醇在水介质中转化为相应的羰基化合物。
  • 硫醇转化为二硫化物。
它还可用作引发剂,引发丙烯腈与衣康酸的共聚反应。
丙烯酰胺凝胶聚合催化剂。

General description

过硫酸铵是一种很容易获得的氧化剂,用于各种化学转化,也被用作化学工业中的漂白剂。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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William H Thiel et al.
Methods in molecular biology (Clifton, N.J.), 1218, 187-199 (2014-10-17)
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Solid state deoximation with ammonium persulfate-silica gel: Regeneration of carbonyl compounds using microwaves.
Varma RS and Meshram HM.
Tetrahedron Letters, 38(31), 5427-5428 (1997)
S Pino et al.
Clinical chemistry, 42(2), 239-243 (1996-02-01)
The chloric acid method is most commonly used to obtain accurate and reproducible measurements of iodine and remove interfering substances. Unfortunately chloric acid is a potential hazard, requiring an explosion-proof hood, among other precautions. We have developed a simple, convenient
Electrical conductivity response of polypyrrole to acetone vapor: effect of dopant anions and interaction mechanisms.
Ruangchuay L, et al.
Synthetic Metals, 140(1), 15-21 (2004)
J M Brewer
Science (New York, N.Y.), 156(3772), 256-257 (1967-04-14)
Ammonium persulfate, a common polymerizing agent for acrylamide gels, can inactivate yeast enolase and produce increased electrophoretic heterogeneity during disc electrophoresis in gels containing 8M urea. The use of riboflavin and light for polymerization or thioglycolate for removal of the

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