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Merck
CN

239216

Sigma-Aldrich

碳酸钙

ACS reagent, ≥99.0%, powder

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About This Item

线性分子式:
CaCO3
CAS号:
分子量:
100.09
Beilstein:
8008338
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥99.0%
等级:
ACS reagent
表单:
powder

等级

ACS reagent

质量水平

方案

≥99.0%

表单

powder

杂质

≤0.002 meq/g water-soluble titr. base
≤0.005% oxidizers
≤0.01% NH4OH pptd.
≤0.01% insol. dil. HCl

pH值(酸碱度)

8

密度

2.93 g/mL at 25 °C (lit.)

痕量阴离子

chloride (Cl-): ≤0.001%
fluoride (F-): ≤0.0015%
sulfate (SO42-): ≤0.01%

痕量阳离子

Ba: ≤0.005%
Fe: ≤0.003%
K: ≤0.01%
Mg: ≤0.02%
NH4+: ≤0.003%
Na: ≤0.1%
Sr: ≤0.1%
heavy metals: ≤0.001% (by ICP-OES)

SMILES字符串

[Ca++].[O-]C([O-])=O

InChI

1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2

InChI key

VTYYLEPIZMXCLO-UHFFFAOYSA-L

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一般描述

CaCO3 天然存在,是石灰石、大理石和白垩的主要成分,可通过氢氧化钙溶液和二氧化碳沉淀制备。

应用

碳酸钙可作为前体制备Pd/CaCO3,它可以作为催化剂用于:
  • Miyaura-Suzuki交叉偶联反应。
  • 通过芳基卤化物和三丁基苯基锡的无配体Stille交叉偶联反应合成联苯。
它还可以作为碱用于Pd催化氟化卤代芳基与烯烃的区域选择性Heck反应合成被取代的烯烃。

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

储存分类代码

11 - Combustible Solids

WGK

nwg

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Michał M Kłosowski et al.
Acta biomaterialia, 20, 129-139 (2015-04-08)
To devise new strategies to treat bone disease in an ageing society, a more detailed characterisation of the process by which bone mineralises is needed. In vitro studies have suggested that carbonated mineral might be a precursor for deposition of
Robert J Friederichs et al.
Journal of the Royal Society, Interface, 12(108), 20150190-20150190 (2015-06-05)
Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and
Eagleson M.
Concise Encyclopedia Chemistry, 162-162 (1994)
Denis Gebauer et al.
Nanoscale, 3(9), 3563-3566 (2011-08-19)
Nanocellulose hybrids are promising candidates for biodegradable multifunctional materials. Hybrids of nanocrystalline cellulose (NCC) and amorphous calcium carbonate (ACC) nanoparticles were obtained through a facile chemical approach over a wide range of compositions. Controlling the interactions between NCC and ACC
Sophie A Jamal et al.
Lancet (London, England), 382(9900), 1268-1277 (2013-07-23)
Phosphate binders (calcium-based and calcium-free) are recommended to lower serum phosphate and prevent hyperphosphataemia in patients with chronic kidney disease, but their effects on mortality and cardiovascular outcomes are unknown. We aimed to update our meta-analysis on the effect of

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