239216
碳酸钙
ACS reagent, ≥99.0%, powder
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线性分子式:
CaCO3
化学文摘社编号:
分子量:
100.09
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
207-439-9
Beilstein/REAXYS Number:
8008338
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder
InChI key
VTYYLEPIZMXCLO-UHFFFAOYSA-L
InChI
1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
SMILES string
[Ca++].[O-]C([O-])=O
grade
ACS reagent
assay
≥99.0%
form
powder
impurities
≤0.002 meq/g water-soluble titr. base, ≤0.005% oxidizers, ≤0.01% NH4OH pptd., ≤0.01% insol. dil. HCl
pH
8
density
2.93 g/mL at 25 °C (lit.)
anion traces
chloride (Cl-): ≤0.001%, fluoride (F-): ≤0.0015%, sulfate (SO42-): ≤0.01%
cation traces
Ba: ≤0.005%, Fe: ≤0.003%, K: ≤0.01%, Mg: ≤0.02%, NH4+: ≤0.003%, Na: ≤0.1%, Sr: ≤0.1%, heavy metals: ≤0.001% (by ICP)
Quality Level
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General description
CaCO3 天然存在，是石灰石、大理石和白垩的主要成分，可通过氢氧化钙溶液和二氧化碳沉淀制备。
Application
碳酸钙可作为前体制备Pd/CaCO3，它可以作为催化剂用于：
- Miyaura-Suzuki交叉偶联反应。
- 通过芳基卤化物和三丁基苯基锡的无配体Stille交叉偶联反应合成联苯。
Other Notes
Legal Information
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
存储类别
11 - Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
Michał M Kłosowski et al.
Acta biomaterialia, 20, 129-139 (2015-04-08)
To devise new strategies to treat bone disease in an ageing society, a more detailed characterisation of the process by which bone mineralises is needed. In vitro studies have suggested that carbonated mineral might be a precursor for deposition of
Robert J Friederichs et al.
Journal of the Royal Society, Interface, 12(108), 20150190-20150190 (2015-06-05)
Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and
Denis Gebauer et al.
Nanoscale, 3(9), 3563-3566 (2011-08-19)
Nanocellulose hybrids are promising candidates for biodegradable multifunctional materials. Hybrids of nanocrystalline cellulose (NCC) and amorphous calcium carbonate (ACC) nanoparticles were obtained through a facile chemical approach over a wide range of compositions. Controlling the interactions between NCC and ACC
Eagleson M.
Concise Encyclopedia Chemistry, 162-162 (1994)
Jane A Cauley et al.
Journal of women's health (2002), 22(11), 915-929 (2013-10-18)
Clinical outcomes of the Women's Health Initiative (WHI) calcium plus vitamin D supplementation trial have been reported during 7.0 years of active intervention. We now report outcomes 4.9 years after the intervention stopped and cumulative findings. Postmenopausal women (N=36,282) were
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