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Merck
CN

239216

Sigma-Aldrich

碳酸钙

ACS reagent, ≥99.0%, powder

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About This Item

线性分子式:
CaCO3
CAS号:
分子量:
100.09
Beilstein:
8008338
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥99.0%
等级:
ACS reagent
表单:
powder

等级

ACS reagent

质量水平

方案

≥99.0%

表单

powder

杂质

≤0.002 meq/g water-soluble titr. base
≤0.005% oxidizers
≤0.01% NH4OH pptd.
≤0.01% insol. dil. HCl

pH值(酸碱度)

8

密度

2.93 g/mL at 25 °C (lit.)

痕量阴离子

chloride (Cl-): ≤0.001%
fluoride (F-): ≤0.0015%
sulfate (SO42-): ≤0.01%

痕量阳离子

Ba: ≤0.005%
Fe: ≤0.003%
K: ≤0.01%
Mg: ≤0.02%
NH4+: ≤0.003%
Na: ≤0.1%
Sr: ≤0.1%
heavy metals: ≤0.001% (by ICP-OES)

SMILES字符串

[Ca++].[O-]C([O-])=O

InChI

1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2

InChI key

VTYYLEPIZMXCLO-UHFFFAOYSA-L

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一般描述

CaCO3 天然存在,是石灰石、大理石和白垩的主要成分,可通过氢氧化钙溶液和二氧化碳沉淀制备。

应用

碳酸钙可作为前体制备Pd/CaCO3,它可以作为催化剂用于:
  • Miyaura-Suzuki交叉偶联反应。
  • 通过芳基卤化物和三丁基苯基锡的无配体Stille交叉偶联反应合成联苯。
它还可以作为碱用于Pd催化氟化卤代芳基与烯烃的区域选择性Heck反应合成被取代的烯烃。

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

储存分类代码

11 - Combustible Solids

WGK

nwg

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Michał M Kłosowski et al.
Acta biomaterialia, 20, 129-139 (2015-04-08)
To devise new strategies to treat bone disease in an ageing society, a more detailed characterisation of the process by which bone mineralises is needed. In vitro studies have suggested that carbonated mineral might be a precursor for deposition of
Robert J Friederichs et al.
Journal of the Royal Society, Interface, 12(108), 20150190-20150190 (2015-06-05)
Experimental chemistry and atomic modelling studies were performed here to investigate a novel ionic co-substitution in hydroxyapatite (HA). Zinc, silicate co-substituted HA (ZnSiHA) remained phase pure after heating to 1100 °C with Zn and Si amounts of 0.6 wt% and
Eagleson M.
Concise Encyclopedia Chemistry, 162-162 (1994)
Denis Gebauer et al.
Nanoscale, 3(9), 3563-3566 (2011-08-19)
Nanocellulose hybrids are promising candidates for biodegradable multifunctional materials. Hybrids of nanocrystalline cellulose (NCC) and amorphous calcium carbonate (ACC) nanoparticles were obtained through a facile chemical approach over a wide range of compositions. Controlling the interactions between NCC and ACC
Jane A Cauley et al.
Journal of women's health (2002), 22(11), 915-929 (2013-10-18)
Clinical outcomes of the Women's Health Initiative (WHI) calcium plus vitamin D supplementation trial have been reported during 7.0 years of active intervention. We now report outcomes 4.9 years after the intervention stopped and cumulative findings. Postmenopausal women (N=36,282) were

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