237078
氯化铝 六水合物
ReagentPlus®, 99%
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关于此项目
经验公式（希尔记法）:
AlCl3 · 6H2O
化学文摘社编号:
分子量:
241.43
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-208-1
MDL number:
Assay:
99%
Form:
crystalline solid
crystals or chunks
crystals or chunks
产品名称
氯化铝 六水合物, ReagentPlus®, 99%
InChI key
JGDITNMASUZKPW-UHFFFAOYSA-K
InChI
1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3
SMILES string
Cl[Al](Cl)Cl.O.O.O.O.O.O
vapor pressure
1 mmHg ( 100 °C)
product line
ReagentPlus®
assay
99%
form
crystalline solid
crystals or chunks
reaction suitability
reagent type: catalyst
core: aluminum
pH
2.5-3.5 (20 °C)
Quality Level
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Application
氯化铝六水合物用作催化剂：
- 用于醇或酚和3,4-二氢-2H-吡喃（DHP）合成对应的THP（四氢吡喃）醚。
- 用于乙酰丙酸和乙醇直接酯化生产乙酰丙酸乙酯。
- 用于由酮和醛合成gem-二氢过氧化物。
General description
氯化铝六水合物是一种不易燃的化合物，广泛用作有机合成中的催化剂。除极易溶于水外，还溶于乙醇、乙醚、甘油、丙二醇和乙腈。它有很多用途，包括原油提炼、生产除臭剂和止汗产品、织物染色、纺织品整理。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
target_organs
Lungs
supp_hazards
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Aluminium (III) chloride hexahydrate: an efficient and versatile reagent in organic synthesis.
Sarma SD, et al.
ARKIVOC (Gainesville, FL, United States), 1, 243-263 (2013)
[Axillary hyperhydrosis. Local treatment with 25% aluminum chloride hexahydrate in absolute alcohol].
F Brandrup et al.
Ugeskrift for laeger, 140(35), 2106-2109 (1978-08-28)
Ingrid Siemund et al.
Contact dermatitis, 77(5), 288-296 (2017-07-12)
Contact allergy to aluminium has been reported more frequently in recent years. It has been pointed out that positive patch test reactions to aluminium may not be reproducible on retesting. To investigate possible variations in patch test reactivity to aluminium
Mark Baranov et al.
Inorganic chemistry, 58(13), 8877-8883 (2019-06-30)
While sophisticated computational methods can predict 31P NMR spectra of phosphorus atoms encapsulated within Keggin-derived heteropoly tungstate and molybdate cluster anions, calculated and experimental chemical shift values typically deviate considerably from one another. Motivated by the observation that experimentally determined
C L Goh
International journal of dermatology, 29(5), 368-370 (1990-06-01)
The efficacy of topical aluminium chloride hexahydrate 20% W/W ethanol (ACH) in the treatment symptomatic palmar hyperhidrosis was studied in 12 patients. A half-sided control single blind (assessor blind) study was done. Patients applied ACH on one palm daily for
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