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蒸汽压
1 mmHg ( 100 °C)
质量水平
产品线
ReagentPlus®
方案
99%
表单
powder
反应适用性
reagent type: catalyst
core: aluminum
pH值(酸碱度)
2.4 (20 °C, 100 g/L)
mp
190 °C (lit.)
SMILES字符串
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
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一般描述
氯化铝是一种醇溶性路易斯酸。† 氯化铝与硼氢化钠在二甘醇中以摩尔比混合,得到具有强还原性属性混合物。† 据报道,它促进 4- 叔丁基苯甲酰氯与均三甲苯之间的 Friedel-Crafts 酰化反应。†
应用
氯化铝用于以下研究:
- 苯聚合生成 p-聚苯。
- 作为 buckymetallocenes 与酸氯化物的 Friedel-Crafts 酰化的催化剂。
- 作为用于测定脂质氢过氧化物的比色法微量测定的催化剂。
特点和优势
氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离,可作为结构材料或化合物使用,具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成,以促进结晶。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
A colorimetric microdetermination of peroxide values utilizing aluminum chloride as the catalyst.
Asakawa T and Matsushita S.
Lipids, 15(11), 965-967 (1980)
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