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Merck
CN

237051

Sigma-Aldrich

氯化铝

ReagentPlus®, 99%

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线性分子式:
AlCl3
CAS号:
分子量:
133.34
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38120507
PubChem化学物质编号:
NACRES:
NA.21

蒸汽压

1 mmHg ( 100 °C)

质量水平

产品线

ReagentPlus®

检测方案

99%

形式

powder

反应适用性

reagent type: catalyst
core: aluminum

pH值(酸碱度)

2.4 (20 °C, 100 g/L)

mp

190 °C (lit.)

SMILES字符串

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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一般描述

氯化铝是一种醇溶性路易斯酸。† 氯化铝与硼氢化钠在二甘醇中以摩尔比混合,得到具有强还原性属性混合物。† 据报道,它促进 4-丁基苯甲酰氯与均三甲苯之间的 Friedel-Crafts 酰化反应。†

应用

氯化铝用于以下研究:
  • 苯聚合生成 p-聚苯。
  • 作为 buckymetallocenes 与酸氯化物的 Friedel-Crafts 酰化的催化剂。
  • 作为用于测定脂质氢过氧化物的比色法微量测定的催化剂。

特点和优势

氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离,可作为结构材料或化合物使用,具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成,以促进结晶。

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

补充剂危害

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

分析证书(COA)

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p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic

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