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Merck
CN

236470

Sigma-Aldrich

三氧化铬(VI)

ACS reagent, ≥98.0%

别名:

铬酸酐

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About This Item

经验公式(希尔记法):
CrO3
CAS号:
分子量:
99.99
EC 号:
MDL编号:
UNSPSC代码:
12352303
PubChem化学物质编号:
NACRES:
NB.24
方案:
≥98.0%
等级:
ACS reagent
表单:
powder or crystals

等级

ACS reagent

质量水平

方案

≥98.0%

表单

powder or crystals

反应适用性

reagent type: oxidant

杂质

≤0.01% insolubles

pH值(酸碱度)

<1 (20 °C, 100 g/L)

mp

196 °C (dec.) (lit.)

痕量阴离子

chloride (Cl-): ≤0.005%
nitrate (NO3-): ≤0.05%
sulfate (SO42-): ≤0.005%

痕量阳离子

Fe, Al, Ba: ≤0.03%
Na: ≤0.2%

SMILES字符串

O=[Cr](=O)=O

InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N

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一般描述

氧化铬(VI)是一种氧化剂,可用于将碳氢键氧化为醇,将烷基芳烃氧化为酮和羧酸,将烯烃氧化为 α, β-不饱和酮,将芳烃氧化为醌,将醇氧化为醛、酮、酸和酮酸

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 1B - Ox. Sol. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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访问文档库

Chromium (VI) Oxide
Freeman F, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Chromium (VI) Oxide.
Freeman F, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2008)
Chromium (VI) oxide-catalyzed oxidation of arenes with periodic acid.
Yamazaki S.
Tetrahedron Letters, 42(19), 3355-3357 (2001)
S Kondo et al.
European journal of biochemistry, 200(3), 689-698 (1991-09-15)
The chemical structure of the saccharide portion of Vibrio parahaemolyticus serotype 012 lipopolysaccharide was studied. Using chemical degradation and modification, as well as methylation analysis in combination with GLC-MS, laser-desorption mass spectrometry and 1H-NMR and 13C-NMR spectroscopy, the carbohydrate backbone
M C García-Rodríguez et al.
Mutation research, 496(1-2), 145-151 (2001-09-12)
The effect of chlorophyllin on micronucleated polychromatic erythrocytes (MN-PCE) induction by chromium trioxide (CrO(3)) exposure in peripheral blood of mice was studied. Animals were treated with a single intraperitoneal dose of chlorophyllin (CHL) (20mg/kg), CrO(3) (20mg/kg), and CHL (20mg/kg) 4h

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