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Merck
CN

234125

Sigma-Aldrich

亚铁氰化铁

别名:

二铁铁素, 亚铁氰化铁, 六氰基铁酸铁, 普鲁士蓝

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About This Item

线性分子式:
Fe4[Fe(CN)6]3
CAS号:
分子量:
859.23
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.55
表单:
powder

表单

powder

质量水平

浓度

≥30% (ICP)

λmax

694 nm

SMILES字符串

[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N

InChI

1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3

InChI key

DNMNDNSFJMUUFM-UHFFFAOYSA-N

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应用

亚铁氰化铁可用于:
  • 作为催化剂催化二氧化碳和环氧化物反应合成环状碳酸酯。
  • 作为前体经热解制备N-掺杂多层石墨烯包裹的Fe-Fe3C纳米颗粒。

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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The crystal structure of Prussian blue: Fe4 [Fe (CN)6]3. xH2O.
Buser HJ, et al.
Inorganic Chemistry, 16(11), 2704-2710 (1977)
Y Vaheb et al.
Journal of nanoscience and nanotechnology, 12(11), 8710-8714 (2013-02-21)
We investigate the assembly of Prussian blue and Cs-Co-Cr Prussian blue analogue molecular nanomagnets into nano-patterned electrodes. Pd or Au gaps - 7-50 nm were fabricated on a SiO2/Si substrate using standard electron beam lithography and lift-off. Nanomagnets were positioned
Prussian blue and its analogues: electrochemistry and analytical applications.
Karyakin AA.
Electroanalysis, 13(10), 813-819 (2001)
Lihua Jin et al.
Chemical communications (Cambridge, England), 49(3), 243-245 (2012-11-24)
A highly robust electrochemically controlled fluorescence switch based on ultrasmall Au nanoclusters has been designed by the aid of the electrochemical redox reaction of prussian blue.
Chen Zhai et al.
Biosensors & bioelectronics, 42, 124-130 (2012-12-04)
In this paper, chitosan-prussian blue-multiwall carbon nanotubes-hollow gold nanospheres (Chit-PB-MWNTs-HGNs) film was fabricated onto the gold electrode surface by one-step electrodeposition method; and then acetylcholinesterase (AChE) and Nafion were modified onto the film to prepare an AChE biosensor. Incorporating MWNTs

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