产品线
ReagentPlus®
表单
powder or crystals
浓度
23.0-26.0% Ni (EDTA titration)
SMILES字符串
[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ni]Cl
InChI
1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2
InChI key
LAIZPRYFQUWUBN-UHFFFAOYSA-L
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一般描述
氯化镍（II）六水合物是一种水合镍盐。其晶体为单斜晶，晶体结构已通过X射线单晶法进行了研究。
应用
氯化镍（II）六水合物可用作以下过程的催化剂：
- 通过芳香醛、苄胺、β-酮酯和硝基烷烃的四组分缩合反应合成四取代的吡咯衍生物。
- 与1,2-乙二硫醇组合用于将四氢吡喃基（THP）和叔丁基二甲基甲硅烷基（TBS）醚脱保护成相应的羟基化合物。
- 通过Biginelli缩合从醛和β-酮酯合成3,4-二氢嘧啶酮。
氯化镍（II）六水合物可用作四取代吡咯衍生物高产率合成的催化剂。它可用于将四氢吡喃基（THP）和叔丁基二甲基甲硅烷基（TBS）醚转化成相应的羟基化合物。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
靶器官
Lungs
储存分类代码
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
此项目有
Catalysis of the Biginelli reaction by ferric and nickel chloride hexahydrates. One-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones.
Lu J and Bai Y.
Synthesis, 2002(04), 0466-0470 (2002)
The Crystal Structure of Nickel Chloride Hexahydrate, NiCl2.6H2O.
Mizuno J.
Journal of the Physical Society of Japan, 16(8), 1571-1580 (1961)
Synthesis of tetra-substituted pyrroles, a potential phosphodiesterase 4B inhibitor, through nickel (II) chloride hexahydrate catalyzed one-pot four-component reaction.
Khan AT, et al.
Tetrahedron Letters, 53(32), 4145-4150 (2012)
A catalytic amount of nickel (II) chloride hexahydrate and 1, 2-ethanedithiol is a good combination for the cleavage of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers.
Khan AT, et al.
Tetrahedron Letters, 45(52), 9617-9621 (2004)
Jenilee Way et al.
Nuclear medicine and biology, 40(3), 430-436 (2013-01-12)
4-[(18)F]Fluorobenzylamine ([(18)F]FBA) is an important building block for the synthesis of (18)F-labeled compounds. Synthesis of [(18)F]FBA usually involves application of strong reducing agents like LiAlH4 which is challenging to handle in automated synthesis units (ASUs). Therefore, alternative methods for the
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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