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Merck
CN

221937

Sigma-Aldrich

碘化铵

greener alternative

ACS reagent, ≥99%

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About This Item

线性分子式:
NH4I
CAS号:
分子量:
144.94
EC 号:
MDL编号:
UNSPSC代码:
12352300
eCl@ss:
38050607
PubChem化学物质编号:

等级

ACS reagent

质量水平

蒸汽压

1 mmHg ( 210.9 °C)

检测方案

≥99%

形式

powder or crystals

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

≤0.005% insolubles

灼烧残渣

≤0.05%

pH值(酸碱度)

4.5-6.5 (25 °C, 50 g/L)

痕量阴离子

Cl- and Br-: ≤0.005%
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.05%

痕量阳离子

Ba: ≤0.002%
Fe: ≤5 ppm
heavy metals (as Pb): ≤0.001%

环保替代产品分类

SMILES字符串

N.I

InChI

1S/HI.H3N/h1H;1H3

InChI key

UKFWSNCTAHXBQN-UHFFFAOYSA-N

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一般描述

我们致力于为您带来符合一项或多项绿色化学十二原则的环保替代产品。本品可用作合成许多杂环化合物的原料,也可用作某些反应的催化剂或氧化还原催化剂。点击此处以获取更多信息。
使用以碘化铵为催化剂的二氧化碳将未活化的氮丙啶高收率和区域选择性转化为恶唑烷酮

应用

可用于温和、高效、更环保的脱硫缩醛反应的催化剂。
可用于温和、高效、更环保的脱硫缩醛反应的催化剂。

溴化钾、盐酸和过氧化氢对活性亚甲基和次甲基化合物进行化学选择性溴化

象形图

Health hazard

警示用语:

Danger

危险声明

危险分类

STOT RE 1 Oral

靶器官

Thyroid

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Jinho Kim et al.
Organic letters, 14(15), 3924-3927 (2012-07-17)
Copper-mediated regioselective cyanation of indoles and 2-phenylpyridines was developed by using ammonium iodide and DMF as the combined source of a cyano unit under "Pd-free" conditions. Mechanistic studies indicate that the reaction of indoles proceeds through a two-step sequence: electrophilic
Simple and regioselective oxyiodination of aromatic compounds with ammonium iodide and Oxone.
Mohan KVVK, et al.
Tetrahedron Letters, 45(43), 8015-8018 (2004)
Low-Frequency Vibrations in Ammonium Iodide and Ammonium Bromide.
Durig JR and Antion DJ.
J. Chem. Phys. , 51(9), 3639-3647 (1969)
Xiaofang Gao et al.
Chemical communications (Cambridge, England), 51(1), 210-212 (2014-11-20)
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed
Jinho Kim et al.
Journal of the American Chemical Society, 134(5), 2528-2531 (2012-01-28)
The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon atom of the cyano unit, respectively. The procedure was successfully extended

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