215473
硝酸铈(IV)铵
ACS reagent, ≥98.5%
别名:
硝酸铈铵
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关于此项目
线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
240-827-6
MDL number:
Assay:
≥98.5%
Grade:
ACS reagent
Form:
powder or crystals
产品名称
硝酸铈(IV)铵, ACS reagent, ≥98.5%
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
SMILES string
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
grade
ACS reagent
assay
≥98.5%
form
powder or crystals
reaction suitability
reagent type: oxidant
impurities
≤0.05% insol. dil. H2SO4
anion traces
chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%
cation traces
Fe: ≤0.005%
Quality Level
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Application
提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
法规信息
危险化学品
此项目有
Carbon-heteroatom bond-forming reactions mediated by cerium (IV) ammonium nitrate: An overview.
Nair V, et al.
Synlett, 14(2), 156-165 (2003)
Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr.
Zolfigol MA, et al.
Monatshefte fur Chemie / Chemical Monthly, 139(8), 895--895- (2008)
Cerium (IV) ammonium nitrate (CAN) as a catalyst in tap water: A simple, proficient and green approach for the synthesis of quinoxalines.
More SV, et al.
Green Chemistry, 8(1), 91-95 (2006)
A New. ALPHA.-Iodination of Ketones Using Iodine-Ammonium Cerium (IV) Nitrate in Alcohol or Acetic Acid.
Horiuchi CA and Kiji S.
Bulletin of the Chemical Society of Japan, 70(2), 421-426 (1997)
Polyethylene glycol (PEG) mediated green synthesis of 2, 5-disubstituted 1, 3, 4-oxadiazoles catalyzed by ceric ammonium nitrate (CAN).
Kidwai M, et al.
Green Chemistry Letters and Reviews, 31(1), 55-59 (2010)
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