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等级
ACS reagent
质量水平
蒸汽压
1.3 mmHg ( 236 °C)
方案
≥99.5%
表单
powder
反应适用性
reagent type: catalyst
core: mercury
还原残留物
≤0.02%
mp
277 °C (lit.)
溶解性
acetic acid: soluble(lit.)
acetone: soluble in salt form(lit.)
alcohol: soluble(lit.)
diethyl ether: passes test
ethyl acetate: soluble(lit.)
glycerol: soluble(lit.)
water: soluble(lit.)
痕量阳离子
Fe: ≤0.002%
SMILES字符串
Cl[Hg]Cl
InChI
1S/2ClH.Hg/h2*1H;/q;;+2/p-2
InChI key
LWJROJCJINYWOX-UHFFFAOYSA-L
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一般描述
Mercury (II) chloride is an inorganic salt commonly used as a catalyst in organic synthesis.
应用
Mercury (II) chloride can be used as a catalyst for the:
- Addition reaction between aromatic amines to terminal acetylenes to give imines, enamines, and 1,2,3,4-tetrahydroquinoline derivatives.
- Cyclization of amidinothioureas with phenyl hydrazine to produce 3-amino-1,2,4-triazole derivatives.
- Cyclization of O-propargyl glycolaldehyde dithioacetals to afford 3-pyranones along with 2,5-dihydrofuran-3-carboxaldehydes through their dithioketals and dithioacetals reaction.
- Reductive dimerization and cyclization of α,β-unsaturated ketones produce functionalized cyclopentanols using N,N-dimethylformamide as solvent.
警示用语:
Danger
危险分类
Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
监管及禁止进口产品
从最新的版本中选择一种:
Toxicology, 443, 152561-152561 (2020-08-18)
Methylmercury (MeHg) is a ubiquitous environmental contaminant and developmental toxicant known to cause a variety of persistent motor and cognitive deficits. While previous research has focused predominantly on neurotoxic MeHg effects, emerging evidence points to a myotoxic role whereby MeHg
Concise Encyclopedia Chemistry, 498-498 (1994)
Mercury(II) Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Free radical biology & medicine, 52(4), 781-793 (2011-12-27)
Mercury compounds exert toxic effects via interaction with many vital enzymes involved in antioxidant regulation, such as selenoenzymes thioredoxin reductase (TrxR) and glutathione peroxidase (GPx). Selenium supplementation can reactivate the mercury-inhibited TrxR and recover the cell viability in vitro. To
Scientific reports, 9(1), 11361-11361 (2019-08-08)
Exposure to chronic ionizing radiation (CIR) from nuclear power plant accidents, acts of terrorism, and space exploration poses serious threats to humans. Fungi are a group of highly radiation-resistant eukaryotes, and an understanding of fungal CIR resistance mechanisms holds the
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