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蒸汽压
1 hPa ( 748 °C)
质量水平
产品线
ReagentPlus®
方案
≥99%
表单
powder
pH值(酸碱度)
7 (20 °C, 10 g/L)
mp
550 °C (lit.)
SMILES字符串
[Li+].[Br-]
InChI
1S/BrH.Li/h1H;/q;+1/p-1
InChI key
AMXOYNBUYSYVKV-UHFFFAOYSA-M
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一般描述
LiBr/三甲基氯硅烷试剂参与醇向溴化物的转换。
应用
溴化锂(LiBr)可用作以下研究的催化剂:
- 通过无溶剂二硫代缩醛反应将(芳族-和α,β-不饱和)醛转化为二硫代缩醛。
- 通过羰基化合物与活性亚甲基化合物的缩合反应合成烯烃。
- β-氨基醇的绿色合成。
- 通过使用LiBr/硝酸铈铵(CAN)试剂系统(作为Br+ 离子来源)进行芳族化合物的化学和区域选择性溴化。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码
13 - Non Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Lithium Bromide, an Inexpensive and Efficient Catalyst for Opening of Epoxide Rings by Amines at Room Temperature under Solvent-Free Condition.
Chakraborti AK, et al.
European Journal of Organic Chemistry, 2004(17), 3597-3600 (2004)
An efficient chemo and regioselective oxidative nuclear bromination of activated aromatic compounds using lithium bromide and ceric ammonium nitrate.
Roy SC, et al.
Tetrahedron Letters, 42(39), 6941-6942 (2001)
Lithium bromide as a new catalyst for carbon-carbon bond formation in the solid state.
Prajapati D, et al.
Journal of the Chemical Society. Perkin Transactions 1, 9, 959-960 (1996)
Lithium bromide-catalyzed highly chemoselective and efficient dithioacetalization of α,β-unsaturated and aromatic aldehydes under solvent-free conditions.
Firouzabadi H, et al.
Synthesis, 58-60 (1999)
Eoghan M Cunnane et al.
ACS applied materials & interfaces, 12(24), 26955-26965 (2020-05-23)
Vascular tissue engineering is aimed at developing regenerative vascular grafts to restore tissue function by bypassing or replacing defective arterial segments with tubular biodegradable scaffolds. Scaffolds are often combined with stem or progenitor cells to prevent acute thrombosis and initiate
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