等级
reagent grade
质量水平
蒸汽压
1.3 mmHg ( 546 °C)
检测方案
97%
形式
powder
反应适用性
reagent type: catalyst
core: copper
pH值(酸碱度)
5 (20 °C, 50 g/L)
bp
1490 °C (lit.)
mp
430 °C (lit.)
溶解性
dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)
SMILES字符串
Cl[Cu]
InChI
1S/ClH.Cu/h1H;/q;+1/p-1
InChI key
OXBLHERUFWYNTN-UHFFFAOYSA-M
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一般描述
Cu 在 CuCl 中以 + 1(亚铜)价态存在。CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似,因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。
应用
作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
氯化铜 (I)(氯化亚铜,CuCl)已用于合成 7-((叔 -丁基二甲基硅基)氧)七-2,4-二炔-1-醇。CuCl 可用于环共轭二烯的立体定向合成。它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Copper (I) Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)
Journal of proteome research, 11(7), 3860-3879 (2012-05-12)
Plant mitochondria are highly responsive organelles that vary their metabolism in response to a wide range of chemical and environmental conditions. Quantitative proteomics studies have begun to allow the analysis of these large-scale protein changes in mitochondria. However studies of
Academic radiology, 18(12), 1561-1568 (2011-11-08)
The aim of this study was to assess copper metabolism of human hepatocellular carcinoma (HCC) with positron emission tomographic (PET) imaging using copper (II)-64 chloride ((64)CuCl(2)) as a tracer. PET imaging of athymic mice (n = 5) bearing extrahepatic HCC
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