质量水平
检测方案
98%
形式
solid
反应适用性
reaction type: click chemistry
reagent type: catalyst
core: copper
mp
504 °C (lit.)
密度
4.71 g/mL at 25 °C (lit.)
SMILES字符串
[Cu]Br
InChI
1S/BrH.Cu/h1H;/q;+1/p-1
InChI key
NKNDPYCGAZPOFS-UHFFFAOYSA-M
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应用
溴化铜 (CuBr) 可用于以下合成：
- 对映体富集、功能化和保护的炔丙基胺
- 含苯并恶嗪侧基的聚氯乙烯
- 含苯并恶嗪侧基的聚丁二烯（PB-苯并恶嗪）
- 单核络合物 [Cu(L)(PPh3)2Br]
- 溴化铜与 N -（ N -辛基）-2-吡啶甲基亚胺共同参与甲基丙烯酸甲酯的活性自由基聚合。
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Copper (I) bromide complexes with heterocyclic thiones and triphenylphosphine as ligands. The X-ray crystal structure of copper (I) pyrimidine-2-thione bis (triphenylphosphine) bromide [Cu (PPh 3) 2 (PymtH) Br].
Lecomte C, et al.
Polyhedron, 8(8), 1103-1109 (1989)
Thermally curable polyvinylchloride via click chemistry.
Kiskan B, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(11), 3512-3518 (2008)
Copper (I) bromide/N-(n-octyl)-2-pyridylmethanimine-mediated living-radical polymerization of methyl methacrylate using carbosilane dendritic initiators.
Hovestad NJ, et al.
Macromolecules, 33(11), 4048-4052 (2000)
Enantioselective synthesis of propargylamines by copper-catalyzed addition of alkynes to enamines.
Christopher Koradin et al.
Angewandte Chemie (International ed. in English), 41(14), 2535-2538 (2002-08-31)
B Podobnik et al.
Bioconjugate chemistry, 26(3), 452-459 (2015-01-30)
The covalent attachment of poly(ethylene glycol) (PEG) to therapeutic proteins is a commonly used approach for extending in vivo half-lives. A potential limitation of this PEGylation strategy is the adverse effect of PEG on conjugate viscosity. Interferon-alpha (IFN) was conjugated
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