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Merck
CN

208566

氯化钛（IV）

ReagentPlus®, 99.9% trace metals basis

别名:

TTC, 四氯化钛

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关于此项目

线性分子式:
TiCl4
化学文摘社编号:
7550-45-0
分子量:
189.68
NACRES:
NA.55
PubChem Substance ID:
329752044
UNSPSC Code:
12352300
EC Number:
231-444-5
MDL number:
MFCD00011267
Assay:
99.9% trace metals basis
Form:
liquid

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产品名称

氯化钛（IV）, ReagentPlus®, 99.9% trace metals basis

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Ti](Cl)(Cl)Cl

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

product line

ReagentPlus®

assay

99.9% trace metals basis

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

Quality Level

200

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Application

与硼氢化钠一起形成有效的试剂，用于还原：
  • 羧酸和酰氯转化为醇类
  • 酰胺、肟和内酰胺与胺
  • 亚砜转化为硫化物
通过改良的 Bouveault 反应活化吡咯烷，改善转化为相应的的 α,α-二甲胺。
钛 (IV) 氯化物 (TiCl4) 被用作 Ag-TiO2 @ 聚乙二醇 (PEG) 纳米颗粒的合成的前体。TiCl 4 也可用作合成 TiO2/Al2O3 二元氧化物材料 和 N-（10-氧代-乙烯基蒽-9-(10H)-亚基）氰酰胺的组分之一。

General description

氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。pH 在 2.5 至 6.0 范围内的 TiCl4中性溶液（通过添加氧化镁作为碱制备）已被用于合成纳米二氧化钛。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

flash_point_f

Not applicable

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014

存储类别

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_c

Not applicable

法规信息

危险化学品
非剧毒-急性毒性1
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBT3425
SHBT3746
SHBT1589
SHBS7586
SHBS6537

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What is Product 208566, Titanium(IV) chloride, soluble in?

    Per the chemicals encyclopedia published by the Royal Society of Chemistry, Titanium(IV) Chloride is soluble in cold water and alcohol.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

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