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CN
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安全信息

208566

Sigma-Aldrich

氯化钛（IV）

ReagentPlus®, 99.9% trace metals basis

别名:

TTC, 四氯化钛

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About This Item

线性分子式:
TiCl4
CAS号:
7550-45-0
分子量:
189.68
EC 号:
231-444-5
MDL编号:
MFCD00011267
UNSPSC代码:
12352300
PubChem化学物质编号:
329752044
NACRES:
NA.55
方案:
99.9% trace metals basis
表单:
liquid

蒸汽压

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

质量水平

100
200

产品线

ReagentPlus®

方案

99.9% trace metals basis

表单

liquid

反应适用性

reagent type: catalyst
core: titanium

沸点

135-136 °C (lit.)

mp

−25 °C (lit.)

密度

1.73 g/mL at 20 °C (lit.)

SMILES字符串

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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相关类别

一般描述

氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。pH 在 2.5 至 6.0 范围内的 TiCl4中性溶液（通过添加氧化镁作为碱制备）已被用于合成纳米二氧化钛。

应用

与硼氢化钠一起形成有效的试剂，用于还原：
  • 羧酸和酰氯转化为醇类
  • 酰胺、肟和内酰胺与胺
  • 亚砜转化为硫化物
通过改良的 Bouveault 反应活化吡咯烷，改善转化为相应的的 α,α-二甲胺。
钛 (IV) 氯化物 (TiCl4) 被用作 Ag-TiO2 @ 聚乙二醇 (PEG) 纳米颗粒的合成的前体。TiCl 4 也可用作合成 TiO2/Al2O3 二元氧化物材料 和 N-（10-氧代-乙烯基蒽-9-(10H)-亚基）氰酰胺的组分之一。

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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象形图

Skull and crossbonesCorrosion
GHS06,GHS05

警示用语：

Danger

危险声明

H314,H330,H335

危险分类

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

EUH014

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品
非剧毒-急性毒性1

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
SHBR8678
SHBQ9571
SHBQ9572
SHBQ6697
SHBQ1519

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What is Product 208566, Titanium(IV) chloride, soluble in?

    Per the chemicals encyclopedia published by the Royal Society of Chemistry, Titanium(IV) Chloride is soluble in cold water and alcohol.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

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TiO
Reduction of some functional groups with titanium (IV) chloride/sodium borohydride.
Kano S, et al.
Synthesis, 1980(09), 695-697 (1980)
Poly [N-(10-oxo-2-vinylanthracen-9(10H)-ylidene) cyanamide] as a novel cathode material for li-organic batteries.
Schmidt D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53(21), 2517-2523 (2015)
Influence of the sol-gel preparation method on the photocatalytic NO oxidation performance of TiO2/Al2O3 binary oxides.
Polat M, et al.
Catalysis Today, 241, 25-32 (2015)
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