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Merck
CN

205540

Sigma-Aldrich

碘化亚铜

98%

别名:

碘化亚铜

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About This Item

经验公式(希尔记法):
CuI
CAS号:
分子量:
190.45
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38150105
PubChem化学物质编号:
NACRES:
NA.21
方案:
98%
表单:
powder

蒸汽压

10 mmHg ( 656 °C)

质量水平

方案

98%

表单

powder

反应适用性

reaction type: click chemistry
reagent type: catalyst
core: copper

mp

605 °C (lit.)

密度

5.62 g/mL at 25 °C (lit.)

SMILES字符串

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI key

LSXDOTMGLUJQCM-UHFFFAOYSA-M

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相关类别

应用

硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。

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警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral

靶器官

Thyroid

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Simon P H Mee et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(11), 3294-3308 (2005-03-24)
The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Alkynyl sulfides and selenides from alkynyl bromides and diorganoyl chalcogenides promoted by copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(3), 393-394 (1993)
The high-temperature structural behaviour of copper (I) iodide.
Keen DA and Hull S.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 7(29), 5793-5793 (1995)
Convenient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes and prenylchalcogenyl halides in the presence of copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(50), 8041-8042 (1993)
Novel preparation of σ-alkynyl complexes of transition metals by copper (I) iodide-catalysed dehydrohalogenation.
Sonogashira K, et al.
Journal of the Chemical Society. Chemical Communications, 9, 291-292 (1977)

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