蒸汽压
10 mmHg ( 656 °C)
质量水平
检测方案
98%
形式
powder
反应适用性
reaction type: click chemistry
reagent type: catalyst
core: copper
mp
605 °C (lit.)
密度
5.62 g/mL at 25 °C (lit.)
SMILES字符串
[Cu+].[I-]
InChI
1S/Cu.HI/h;1H/q+1;/p-1
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
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应用
硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。
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产品编号
说明
价格
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
靶器官
Thyroid
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Simon P H Mee et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(11), 3294-3308 (2005-03-24)
The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Alkynyl sulfides and selenides from alkynyl bromides and diorganoyl chalcogenides promoted by copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(3), 393-394 (1993)
The high-temperature structural behaviour of copper (I) iodide.
Keen DA and Hull S.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 7(29), 5793-5793 (1995)
Roberta Berrino et al.
The Journal of organic chemistry, 77(5), 2537-2542 (2012-01-31)
Free NH 3,3-diarylacrylamides are cyclized to substituted 2-quinolones in the presence of CuI, PPh(3), and KO-t-Bu in o-xylene at 100 °C. The reaction proceeds through a C-H functionalization/C-N bond formation process. With unsymmetrical 3,3-diarylacrylamides, high selectivity is observed using substrates
Novel preparation of σ-alkynyl complexes of transition metals by copper (I) iodide-catalysed dehydrohalogenation.
Sonogashira K, et al.
Journal of the Chemical Society. Chemical Communications, 9, 291-292 (1977)
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