205540
碘化亚铜
98%
别名:
碘化亚铜
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关于此项目
经验公式（希尔记法）:
CuI
化学文摘社编号:
分子量:
190.45
PubChem Substance ID:
eCl@ss:
38150105
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-674-6
MDL number:
Assay:
98%
Form:
powder
产品名称
碘化亚铜, 98%
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
InChI
1S/Cu.HI/h;1H/q+1;/p-1
SMILES string
[Cu+].[I-]
vapor pressure
10 mmHg ( 656 °C)
assay
98%
form
powder
reaction suitability
reaction type: click chemistry
reagent type: catalyst
core: copper
mp
605 °C (lit.)
density
5.62 g/mL at 25 °C (lit.)
Quality Level
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Application
硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
target_organs
Thyroid
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
The high-temperature structural behaviour of copper (I) iodide.
Keen DA and Hull S.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 7(29), 5793-5793 (1995)
Simon P H Mee et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(11), 3294-3308 (2005-03-24)
The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Alkynyl sulfides and selenides from alkynyl bromides and diorganoyl chalcogenides promoted by copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(3), 393-394 (1993)
Convenient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes and prenylchalcogenyl halides in the presence of copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(50), 8041-8042 (1993)
Novel preparation of σ-alkynyl complexes of transition metals by copper (I) iodide-catalysed dehydrohalogenation.
Sonogashira K, et al.
Journal of the Chemical Society. Chemical Communications, 9, 291-292 (1977)
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