登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式(希尔记法):
CuI
化学文摘社编号:
分子量:
190.45
PubChem Substance ID:
eCl@ss:
38150105
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-674-6
MDL number:
Assay:
98%
Form:
powder
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
InChI
1S/Cu.HI/h;1H/q+1;/p-1
SMILES string
[Cu+].[I-]
vapor pressure
10 mmHg ( 656 °C)
assay
98%
form
powder
reaction suitability
reaction type: click chemistry, reagent type: catalyst
core: copper
mp
605 °C (lit.)
density
5.62 g/mL at 25 °C (lit.)
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
target_organs
Thyroid
flash_point_f
Not applicable
flash_point_c
Not applicable
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
Simon P H Mee et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(11), 3294-3308 (2005-03-24)
The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Alkynyl sulfides and selenides from alkynyl bromides and diorganoyl chalcogenides promoted by copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(3), 393-394 (1993)
The high-temperature structural behaviour of copper (I) iodide.
Keen DA and Hull S.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 7(29), 5793-5793 (1995)
Novel preparation of σ-alkynyl complexes of transition metals by copper (I) iodide-catalysed dehydrohalogenation.
Sonogashira K, et al.
Journal of the Chemical Society. Chemical Communications, 9, 291-292 (1977)
Roberta Berrino et al.
The Journal of organic chemistry, 77(5), 2537-2542 (2012-01-31)
Free NH 3,3-diarylacrylamides are cyclized to substituted 2-quinolones in the presence of CuI, PPh(3), and KO-t-Bu in o-xylene at 100 °C. The reaction proceeds through a C-H functionalization/C-N bond formation process. With unsymmetrical 3,3-diarylacrylamides, high selectivity is observed using substrates
我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持


