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蒸汽密度
2.55 (vs air)
质量水平
蒸汽压
165 mmHg ( 20 °C)
产品线
ReagentPlus®
方案
99%
表单
liquid
自燃温度
936 °F
expl. lim.
16 %
dilution
(for general lab use)
折射率
n20/D 1.361 (lit.)
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一般描述
Its IR spectra in the vapor phase and in solution form (in CS2 and CCl4) have been reported.[1] It can be synthesized from dimethyl ether via carbonylation in the presence of halide-free catalysts based on zeolites.[2] It has also been reported to be formed during the synthesis of poly(vinyl) alcohol (PVA). It undergoes transesterification reaction with n-octanol in the presence of Amberlyst 15 catalyst to afford octyl acetate and methanol.[3]
Methyl acetate is an aliphatic ester that can be prepared via carbonylation of dimethyl ether over zeolites. MA is formed as a by-product during the preparation of polyvinyl alcohol from acetic acid and methanol.[4]
应用
Methyl acetate may be used for the preparation of fatty acid methyl esters and triacetin from rapeseed oil via non-catalytic trans-esterification reaction under super-critical conditions.[5]
Methyl acetate may be used in the following:
- As acyl acceptor in the preparation of biodiesel.[6]
- Synthesis of ethanol.[7]
- Preparation of n-butyl acetate, via transesterification reaction with n-butanol in the presence of acidic catalysts.[3]
- acetic anhydride
- methyl acrylate
- vinyl acetate
- ethyl amide
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
8.6 °F - closed cup
闪点(°C)
-13 °C - closed cup
法规信息
危险化学品
Kinetics of transesterification of methyl acetate and n-octanol catalyzed by cation exchange resins.
Liu Y, et al.
Korean Journal of Chemical Engineering, 30(5), 1039-1042 (2013)
Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis.
Zuo C, et al.
Industrial & Engineering Chemistry Research, 53(26), 10540-10548 (2014)
Samuel Barak et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(7), 3451-3460 (2020-02-06)
Soot emissions in combustion are unwanted consequences of burning hydrocarbon fuels. The presence of soot during and following combustion processes is an indication of incomplete combustion and has several negative consequences including the emission of harmful particulates and increased operational
Synthesis of ethanol from methanol and syngas through an indirect route containing methanol dehydrogenation, DME carbonylation, and methyl acetate hydrogenolysis.
Liu Y, et al.
Fuel Processing Technology, 110, 206-213 (2013)
Dimethyl ether carbonylation to methyl acetate over HZSM-35.
Liu J, et al.
Catalysis Letters, 139(1-2), 33-37 (2010)
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