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等级
ACS reagent
质量水平
方案
≥98.0%
表单
powder
反应适用性
reagent type: catalyst
core: mercury
杂质
≤0.01% insolubles
还原残留物
≤0.02%
mp
179-182 °C (lit.)
痕量阴离子
chloride (Cl-): ≤0.005%
nitrate (NO3-): ≤0.005%
sulfate (SO42-): ≤0.005%
痕量阳离子
Fe: ≤0.001%
Hg+: ≤0.4%
other heavy metals (as Pb): ≤0.002%
SMILES字符串
CC(=O)O[Hg]OC(C)=O
InChI
1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI key
BRMYZIKAHFEUFJ-UHFFFAOYSA-L
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一般描述
Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.
Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.
应用
Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions. Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.
Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones). It may be used in the hydrothermal synthesis of [Hg2(apca)2]n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg22 + dumbbell.
警示用语：
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
监管及禁止进口产品
Mercury (II) Acetate.
Dejmek M.
Synlett, 23(19), 2867-2868 (2012)
Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
J. Electroanal. Chem. Interfac. Electrochem., 25(3), 397-408 (1973)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Mercury (II) acetate-Nafion modified electrode for anodic stripping voltammetry of lead and copper with flow-injection analysis.
Dalangin RR and Gunasingham H.
Analytica Chimica Acta, 291(1), 81-87 (1994)
In situ hydrothermal synthesis of 2D mercury (I)-organic framework from 3-aminopyrazine-2-carboxylic acid and mercury (II) acetate.
Dehghanpour S, et al.
Inorganic Chemistry Communications, 25, 79-82 (2012)
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