12849
硫酸铜 五水合物
puriss., suitable for, meets analytical specification of Ph. Eur., BP, USP,FCC
别名:
Cupric sulfate 五水合物, 硫酸，铜（II）盐（1：1）五水合物
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关于此项目
线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
蒸汽压
7.3 mmHg ( 25 °C)
质量水平
等级
puriss.
方案
98.5-100.5% (USP)
表单
crystals
质量
meets analytical specification of Ph. Eur., BP, USP,FCC
缺失
35.0-36.5% loss on drying, 250 °C
pH值（酸碱度）
3.5-4.5 (20 °C, 50 g/L)
mp
110 °C (dec.) (lit.)
痕量阴离子
chloride (Cl-): ≤100 mg/kg
痕量阳离子
As: ≤5 mg/kg
Ca: ≤50 mg/kg
Fe: ≤30 mg/kg
K: ≤100 mg/kg
Mg: ≤50 mg/kg
Na: ≤200 mg/kg
Ni: ≤50 mg/kg
Pb: 4 ppm
适用性
passes test for appearance of solution
suitable for
SMILES字符串
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
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一般描述
五水硫酸铜（II）（CuSO4·5H2O，胆矾）是一种水合铜（II）盐。它能与三脚架配体发生水热反应，产生金属-有机骨架（MOF）。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后，它会分解成CuO。
应用
五水硫酸铜（II）可用于以下研究：
- 在无溶剂条件下作为醇和酚乙酰化的催化剂。
- 制备用于Cu-Zn-Sn前体电沉积的电解质，它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
- 作为乙醇的脱水反应的催化剂。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Preparation of Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors.
Araki H, et al.
Physica Status Solidi, 6(5), 1266-1268 (2009)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
William C Kwan et al.
The Journal of comparative neurology, 527(3), 558-576 (2018-01-03)
The primate visual brain possesses a myriad of pathways, whereby visual information originating at the retina is transmitted to multiple subcortical areas in parallel, before being relayed onto the visual cortex. The dominant retinogeniculostriate pathway has been an area of
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