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Merck
CN

12849

Sigma-Aldrich

硫酸铜 五水合物

puriss., suitable for, meets analytical specification of Ph. Eur., BP, USP,FCC

别名:

Cupric sulfate 五水合物, 硫酸,铜(II)盐(1:1)五水合物

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About This Item

线性分子式:
CuSO4 · 5H2O
CAS号:
分子量:
249.69
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
方案:
98.5-100.5% (USP)
表单:
crystals

蒸汽压

7.3 mmHg ( 25 °C)

质量水平

等级

puriss.

方案

98.5-100.5% (USP)

表单

crystals

质量

meets analytical specification of Ph. Eur., BP, USP,FCC

缺失

35.0-36.5% loss on drying, 250 °C

pH值(酸碱度)

3.5-4.5 (20 °C, 50 g/L)

mp

110 °C (dec.) (lit.)

痕量阴离子

chloride (Cl-): ≤100 mg/kg

痕量阳离子

As: ≤5 mg/kg
Ca: ≤50 mg/kg
Fe: ≤30 mg/kg
K: ≤100 mg/kg
Mg: ≤50 mg/kg
Na: ≤200 mg/kg
Ni: ≤50 mg/kg
Pb: 4 ppm

适用性

passes test for appearance of solution
suitable for

SMILES字符串

O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O

InChI

1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

InChI key

JZCCFEFSEZPSOG-UHFFFAOYSA-L

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一般描述

五水硫酸铜(II)(CuSO4·5H2O,胆矾)是一种水合铜(II)盐。它能与三脚架配体发生水热反应,产生金属-有机骨架(MOF)。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后,它会分解成CuO。

应用

五水硫酸铜(II)可用于以下研究:
  • 在无溶剂条件下作为醇和酚乙酰化的催化剂。
  • 制备用于Cu-Zn-Sn前体电沉积的电解质,它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
  • 作为乙醇的脱水反应的催化剂。

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Damijana Urankar et al.
Journal of combinatorial chemistry, 10(6), 981-985 (2008-10-17)
Azoamides, previously established as bioactive intracellular GSH-depleting agents, were decorated with a terminal alkyne moiety to 4 and then were transformed, by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC), into different ligand-arm functionalized azoamides 6. Azides 5 having ligand-arms amenable for binding to
Preparation of Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors.
Araki H, et al.
Physica Status Solidi, 6(5), 1266-1268 (2009)

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