12634
氯酸钾
puriss., 99-101%
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线性分子式:
KClO3
化学文摘社编号:
分子量:
122.55
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
223-289-7
MDL number:
Assay:
99-101%
Form:
powder or crystals
InChI key
VKJKEPKFPUWCAS-UHFFFAOYSA-M
InChI
1S/ClHO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
SMILES string
[K+].[O-]Cl(=O)=O
grade
puriss.
assay
99-101%
form
powder or crystals
impurities
≤0.001% heavy metals (as Pb)
pH
5-6.5 (25 °C, 61.3 g/L)
mp
356 °C (lit.)
anion traces
chloride (Cl-): ≤100 mg/kg, sulfate (SO42-): ≤100 mg/kg
cation traces
As: ≤2 mg/kg, Ca: ≤50 mg/kg, Fe: ≤30 mg/kg
Quality Level
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General description
Crystals of potassium chlorate belong to the monoclinic crystal system. On heating above 400°C, it degrades to give potassium chloride and potassium perchlorate. It has strong oxidizing properties. On exposure to X-rays, oxygen-17 enriched KClO3 generates O3- radical, which was investigated by ESR (Electron Spin Resonance). Irradiation of potassium chlorate with X-ray causes the degradation to generate chloride, chlorite, hypochlorite and occluded oxygen. Significant quantities of dichlorine hexoxide and a trace of chlorine dioxide were also produced.
Application
Potassium chlorate may be used in the preparation of graphite oxide (GO).
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Ox. Sol. 1
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
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The Decomposition of Solid Potassium Chlorate by X Rays.
Heal HG.
Canadian Journal of Chemistry, 37(5), 979-987 (1959)
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Chemistry of Materials, 19(18), 4396-4404 (2007)
ESR Spectrum of O-3 Trapped in a Single Crystal of Potassium Chlorate.
Schlick S.
J. Chem. Phys. , 56, 654-661 (1972)
Kazutomo Ishi et al.
Bioscience, biotechnology, and biochemistry, 69(12), 2463-2465 (2005-12-27)
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Paola González Audino et al.
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The stability to heart of cis-permethrin and beta-cypermethrin in the solid phase was studied and the decomposition products identified. Samples heated at 210 degrees C in an oven in the dark showed that, in the absence of potassium chlorate (the
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