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质量水平
等级
puriss.
方案
≥98%
反应适用性
reagent type: catalyst
core: zinc
mp
394 °C (lit.)
痕量阴离子
sulfate (SO42-): ≤100 mg/kg
痕量阳离子
Ba: ≤10 mg/kg
Ca: ≤100 mg/kg
Fe: ≤10 mg/kg
K: ≤100 mg/kg
Mg: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
SMILES字符串
Br[Zn]Br
InChI
1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI key
VNDYJBBGRKZCSX-UHFFFAOYSA-L
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一般描述
溴化锌是一种无机盐。负载在羟基磷灰石上的溴化锌（Zn-HAP）可促进3-取代吲哚的合成。
应用
溴化锌（ZnBr2）可用于以下研究：
- 从脱氧核苷中除去二甲氧基三苯甲基醚。
- 除去核苷衍生物中的N-酰基保护基。
- 不饱和酮和酯的O-甲硅烷基化二烯酸酯的烷基化。
- 作为催化剂用于合成α-全氟烷基化高烯丙醇。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
The use of zinc bromide for removal of dimethoxytrityl ethers from deoxynucleosides.
Matteucci MD and Caruthers MH.
Tetrahedron Letters, 31(34), 3243-3246 (1984)
Zinc bromide promoted allylation of aluminum acetals derived from perfluoro carboxylic acid esters and diisobutylaluminum hydride. New convenient access to a-perfluoroalkylated homoallyl alcohols.
Ishihara T, et al.
Tetrahedron Letters, 34(36), 5777-5777 (1993)
γ-Alkylation of unsaturated ketones and esters: zinc bromide-catalysed alkylation of O-silylated dienolates.
Fleming I, et al.
Tetrahedron Letters, 20(34), 3209-3212 (1979)
Zinc bromide supported on hydroxyapatite as a new and efficient solid catalyst for Michael addition of indoles to electron-deficient olefins.
Tahir R, et al.
J. Mol. Catal. A: Chem., 246(1), 39-42 (2006)
J R Baker et al.
Organic letters, 9(1), 45-48 (2006-12-29)
[reaction: see text] A key structural feature of the Neocarzinostatin chromophore is a reactive epoxydiyne. We present here a new method for the preparation of epoxydiynes by the addition of an allenyl zinc bromide to a propargylic ketone.
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