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等级
ACS reagent
质量水平
方案
≥99.5%
表单
powder, crystals or granules
反应适用性
reagent type: catalyst
core: boron
澄清度
passes test
缺失
≤0.5% loss on drying
pH值(酸碱度)
8 (20 °C, 50 g/L)
SMILES字符串
[Na+].c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
InChI key
HFSRCEJMTLMDLI-UHFFFAOYSA-N
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一般描述
在催化过程中,NaBPh4 是一种方便的苯基来源,可以用于合成苯基化产物。
应用
四苯硼钠可与胺、铵离子和大碱金属离子(如铯或铷离子)形成疏水盐。因此,它通常在重量分析中用作沉淀剂。
通过离子交换得到稳定的、结晶性N-酰胺盐。与三氟甲磺酸乙烯基酯或芳基酯偶联形成芳烯烃和联芳基化合物。
警示用语:
Danger
危险声明
危险分类
Acute Tox. 3 Oral
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Rhodium-catalyzed phenylation of N-arylsulfonyl aldimines with sodium tetraphenylborate or trimethyl (phenyl) stannane
Ueda M and Miyaura N
Journal of Organometallic Chemistry, 595(1), 31-35 (2000)
The Journal of Organic Chemistry, 57, 5136-5136 (1992)
Recovery of ammonium and cesium ions from aqueous waste streams by sodium tetraphenylborate.
Ponder SM & Mallouk TE.
Industrial & Engineering Chemistry Research, 38(10), 4007-4010 (1999)
Tetrahedron Letters, 33, 4815-4815 (1992)
D C Kapsimali et al.
Talanta, 80(3), 1311-1317 (2009-12-17)
Two different derivatizing reagents were tested for the development of a fast and sensitive method for the determination of selenites (Se(IV)) in human urine. The reagents were sodium tetraethylborate (NaBEt(4)) and tetraphenylborate (NaBPh(4)), respectively, and the procedure is based on
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