蒸汽密度
3.6 (vs air)
质量水平
蒸汽压
12.4 mmHg ( 37.7 °C)
4.3 mmHg ( 15 °C)
产品线
ReagentPlus®
检测方案
≥99%
形式
liquid
自燃温度
914 °F
包含
4-tert-butylcatechol as stabilizer
expl. lim.
6.1 %
折射率
n20/D 1.546 (lit.)
bp
145-146 °C (lit.)
mp
−31 °C (lit.)
密度
0.906 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
C=Cc1ccccc1
InChI
1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
InChI key
PPBRXRYQALVLMV-UHFFFAOYSA-N
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一般描述
已有对从纺织印染废水处理厂(TDWTP)中除去苯乙烯的研究。Co-SBA-15在过氧化氢氧化苯乙烯过程中的催化潜力已有研究。通过气相色谱-质谱(GC-MS)和选择离子监测(SIM)对苯乙烯的不对称环氧化进行筛选已有报道。通过使用增溶的4,4′-二烷基取代的2,2′-联吡啶,可对苯乙烯进行均相原子转移自由基聚合(ATRP) ,从而生成成分确定的聚合物。使用催化钯/碳,氯苯和取代的氯苯与苯乙烯在水中的Heck反应,可得到1,2-二苯基乙烷。
应用
苯乙烯已用于制备成分确定的叔-丙烯酸丁酯、丙烯酸甲酯和苯乙烯的均聚物、二嵌段共聚物和三嵌段共聚物 。
苯乙烯已被用作测试苯乙烯样品,该研究涉及在聚(苯乙烯-嵌段-二甲基硅氧烷)(PSDMS)作为稳定剂存在下,可逆加成-断裂链转移(RAFT)控制子对苯乙烯在超临界二氧化碳中的RAFT聚合作用的影响。
其他说明
抑制剂随着时间的推移而逐渐消耗,特别是在较高温度条件下
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3
靶器官
hearing organs, Respiratory system
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Se pu = Chinese journal of chromatography, 32(12), 1385-1389 (2015-04-24)
A screening method by gas chromatography-mass spectrometry (GC-MS) with selected ion monitoring (SIM) has been developed for asymmetric epoxidation of styrene. All samples were analyzed by GC-MS with the mode of SIM by using ethylbenzene as the internal standard, by
Journal of nanoscience and nanotechnology, 14(9), 7234-7241 (2015-05-01)
The rapid preparation of SBA-15 with cobalt (Co) introduction was performed via the ultrasonic irradiation in combination with "pH-adjusting" method. The catalytic properties of the synthesized Co-SBA-15 were investigated by examining the oxidation of styrene with hydrogen peroxide. The effect
The preparation of t-butyl acrylate, methyl acrylate, and styrene block copolymers by atom transfer radical polymerization: Precursors to amphiphilic and hydrophilic block copolymers and conversion to complex nanostructured materials.
Journal of Polymer Science Part A: Polymer Chemistry, 38(S1), 4805-4820 (2000)
Heterogeneous palladium-catalysed heck reaction of aryl chlorides and styrene in water under mild conditions.
Advanced Synthesis & Catalysis, 344(3-4), 348-354 (2002)
Effect of stabilizer concentration and controller structure and composition on polymerization rate and molecular weight development in RAFT polymerization of styrene in supercritical carbon dioxide.
Polymer, 50(21), 5024-5030 (2009)
商品
Heck反应是烯烃与芳基或乙烯基卤化物(或三氟甲磺酸酯)之间的钯催化交叉偶联反应,用于生成取代的烯烃。
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