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Merck
CN

D186309

硫酸二甲酯

≥99.5%, liquid

别名:

二甲基硫酸酯

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关于此项目

线性分子式:
(CH3O)2SO2
化学文摘社编号:
分子量:
126.13
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-058-1
MDL number:
Beilstein/REAXYS Number:
635994
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产品名称

硫酸二甲酯, ≥99.5%

InChI key

VAYGXNSJCAHWJZ-UHFFFAOYSA-N

InChI

1S/C2H6O4S/c1-5-7(3,4)6-2/h1-2H3

SMILES string

COS(=O)(=O)OC

vapor density

4.3 (vs air)

vapor pressure

0.7 mmHg ( 25 °C)

assay

≥99.5%

form

liquid

autoignition temp.

923 °F

refractive index

n20/D 1.386 (lit.)

bp

188 °C (lit.)

mp

−32 °C (lit.)

density

1.333 g/mL at 25 °C (lit.)

Quality Level

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Application

硫酸二甲酯可与氧化铝一起用于制备醇、酚和羧酸的单甲基化衍生物。它也可与二甲基甲酰胺 (DMF) 结合形成甲氧基-亚甲基- N , N -二甲基亚铁盐,可用于制备β-内酰胺类。

Packaging

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18 L Kilo-Lab ®包装并非所有领域均可用。

Legal Information

Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

181.4 °F - closed cup

flash_point_c

83 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A new method for sequencing DNA.
Maxam AM and Gilbert W.
Proceedings of the National Academy of Sciences of the USA, 74(2), 560-564 (1977)
DMF-dimethyl sulfate as a new reagent for the synthesis of β-lactams.
Jarrahpour A and Zarei M.
Tetrahedron Letters, 50(14), 1568-1570 (2009)
Methylation of alcohols, phenols, and carboxylic acids, and selective monomethylation of diols and dicarboxylic acids with dimethyl sulfate by use of alumina.
Ogawa H, et al.
Bulletin of the Chemical Society of Japan, 59(8), 2481-2483 (1986)
Chad M Kurylo et al.
Cell reports, 25(1), 236-248 (2018-10-04)
Prevailing dogma holds that ribosomes are uniform in composition and function. Here, we show that nutrient limitation-induced stress in E. coli changes the relative expression of rDNA operons to alter the rRNA composition within the actively translating ribosome pool. The most
Kwang Sun Ryu et al.
The journal of physical chemistry. B, 111(4), 731-739 (2007-01-26)
The physical properties of polyaniline (PAn) powder, doped by nucleophilic doping of dimethyl sulfate (DMS), were characterized, as well as its electrochemical behaviors, to investigate the possibility of a power source device adopting the PAn-DMS electrodes. It is shown that

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