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Merck
CN

93742

Supelco

五氟苯肼

for HPLC derivatization, LiChropur, ≥98.0% (GC)

别名:

NSC 88334, PFPH, (全氟苯基)肼

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About This Item

线性分子式:
C6F5NHNH2
CAS号:
分子量:
198.09
Beilstein:
747800
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22

等级

for HPLC derivatization

质量水平

方案

≥98.0% (GC)
98.0-102.0% (wt., NT)

表单

crystals

质量

LiChropur

技术

HPLC: suitable

mp

74-76 °C (lit.)

SMILES字符串

NNc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C6H3F5N2/c7-1-2(8)4(10)6(13-12)5(11)3(1)9/h13H,12H2

InChI key

BYCUWCJUPSUFBX-UHFFFAOYSA-N

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应用

Pentafluorophenylhydrazine may be used as a derivatizing agent in the determination of semi-volatile carbonyl compounds in air and human plasma samples, using high-resolution gas chromatography coupled with gas chromatography (HRGC-MS) and liquid chromatography atmospheric-pressure chemical-ionization mass spectrometry (LC-APCI-MS-MS), respectively.

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法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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分析证书(COA)

Lot/Batch Number

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J F Sheen et al.
Analytical and bioanalytical chemistry, 380(7-8), 891-897 (2005-02-09)
Two carbonyl compounds, nabumetone and testosterone, were derivatized with pentafluorophenyl hydrazine (PFPH) and analyzed by atmospheric-pressure chemical-ionization mass spectrometry. The PFPH derivatives underwent dissociative electron capture in negative-ion APCI (ECAPCI) and gave intense [M-20](-) ions in the mass spectra. In
Pentafluorophenylhydrazine as a coating reagent for the HRGC-MS determination of semi-volatile carbonyl compounds in air
Cecinato A, et al.
Chromatographia, 54(3-4), 263-269 (2001)
Anže Djordjević et al.
Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie, 132, 110877-110877 (2020-10-24)
An unavoidable consequence of cardiac surgery is oxidative stress and resulting peroxidation of biological molecules, in particular unsaturated lipids. The detection of peroxidation metabolites in biological environments is difficult due to their large variety, small concentration, and high reactivity. One
Chemical derivatization to enhance ionization of anabolic steroids in LC-MS for doping-control analysis.
Athanasiadou, I., et al.
Trends in Analytical Chemistry, 42, 137-156 (2013)

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