93510
(S)-Trolox 甲醚
derivatization grade (chiral), LiChropur™, ≥98.0%
别名:
(S)-6-甲氧基-2,5,7,8-四甲基色烷-2-羧酸
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关于此项目
经验公式（希尔记法）:
C15H20O4
化学文摘社编号:
分子量:
264.32
UNSPSC Code:
41115710
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5481541
Assay:
≥98.0% (sum of enantiomers, HPLC), ≥98.0%
Form:
powder
InChI
1S/C15H20O4/c1-8-9(2)13-11(10(3)12(8)18-5)6-7-15(4,19-13)14(16)17/h6-7H2,1-5H3,(H,16,17)/t15-/m0/s1
SMILES string
COc1c(C)c(C)c2O[C@@](C)(CCc2c1C)C(O)=O
InChI key
MNBMVDGIDVXTOF-HNNXBMFYSA-N
grade
derivatization grade (chiral)
assay
≥98.0% (sum of enantiomers, HPLC), ≥98.0%
form
powder
optical activity
[α]20/D −69±2°, c = 1% in ethanol
optical purity
enantiomeric ratio: ≥99.5:0.5 (HPLC)
quality
LiChropur™
technique(s)
HPLC: suitable
mp
143-145 °C
Quality Level
General description
(S)-Trolox 甲醚是一种手性衍生剂，用于将对映异构体衍生为非对映异构体。
Application
(S)-Trolox 甲醚可用作手性衍生试剂，用于以下用途：
- 通过毛细管气相色谱（GC）和超临界流体色谱（SFC）分析手性醇
- 使用气相色谱（GC）、超临界流体色谱（SFC）和亚临界流体色谱技术对几种苯二氮卓类药物进行对映体分离
Packaging
无底玻璃瓶。内含物装在锥底内插管中。
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
W. Walther et al.
J. Microcol. Sep., 4, 45-45 (1992)
Direct and indirect approaches to enantiomeric separation of benzodiazepines using micro column techniques
Almquist RS, et al.
Journal of Chromatography A, 679(1), 139-146 (1994)
Design and development of chiral reagents for the chromatographic ee determination of chiral alcohols
Walther W and Netscher T
Chirality, 8(5), 397-401 (1996)
W. Walther et al.
Chimia, 45, 121-121 (1991)
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