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Merck
CN

93000

Sigma-Aldrich

三苯基氯甲烷

purum, ≥97.0% (HPLC), ≥97.0% (AT)

别名:

三苯基甲基氯, 氯三苯甲烷, 氯代三苯甲烷

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About This Item

线性分子式:
(C6H5)3CCl
CAS号:
分子量:
278.78
Beilstein:
397363
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

等级

purum

质量水平

方案

≥97.0% (AT)
≥97.0% (HPLC)

表单

powder

灼烧残渣

≤0.2% (as SO4)

沸点

230-235 °C/20 mmHg (lit.)

mp

109-112 °C (lit.)
109-113 °C

溶解性

chloroform: 0.1 g/mL, clear

官能团

chloro
phenyl

SMILES字符串

ClC(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

JBWKIWSBJXDJDT-UHFFFAOYSA-N

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应用

  • Organic Synthesis: Research on the synthesis of 1, 2, 4-triazine derivatives, exploring the condensation reactions of trityl chloride with various compounds (Majid et al., 2020).

其他说明

用于三苯甲基化的试剂;对敏感化合物进行三苯甲基化和随后的去三苯甲基化的有效方法

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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S J Harding et al.
Journal of peptide science : an official publication of the European Peptide Society, 5(8), 368-373 (1999-10-03)
A rational attempt to prepare FmocHis(piTrt)OH regiospecifically gave in fact the well-known tau-trityl isomer, and experiments with model systems indicate that the prospects for access to pi-trityl histidine derivatives, which would be of great value for the racemization-free synthesis of
Vijayavitthal T Mathad et al.
Natural product research, 20(12), 1053-1058 (2006-11-28)
Jones oxidation of Andrographolide (1), gave mixture of three products (3-dehydroandrographolide (5), 3,19-bis dehydroandrographolide (6) and 19-dehydroandrographolide (7). Tritylation of andrographolide at C19-OH resulted to products 8 and diene 9, which can be converted to its acetate 10 and oxidation
K. Barlos et al.
The Journal of Organic Chemistry, 47, 1324-1324 (1982)
Ryuichi Hasegawa et al.
Congenital anomalies, 45(4), 137-145 (2005-12-20)
To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 days starting at 5-6 weeks of age respectively, under
R Hasegawa et al.
Regulatory toxicology and pharmacology : RTP, 47(3), 296-307 (2006-12-13)
We comprehensively re-analyzed the toxicity data for 18 industrial chemicals from repeated oral exposures in newborn and young rats, which were previously published. Two new toxicity endpoints specific to this comparative analysis were identified, the first, the presumed no observed

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