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Merck
CN

92732

Supelco

三甲基氢氧化硫 溶液

~0.25 M in methanol, for GC derivatization, LiChropur

别名:

TMSH

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About This Item

线性分子式:
(CH3)3S(OH)
CAS号:
分子量:
94.18
Beilstein:
3910286
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22

等级

for GC derivatization

质量水平

表单

liquid

质量

LiChropur

反应适用性

reagent type: derivatization reagent
reaction type: Alkylations

包装

pkg of 10 × 1 mL

浓度

~0.25 M in methanol

技术

gas chromatography (GC): suitable

储存温度

2-8°C

SMILES字符串

[OH-].C[S+](C)C

InChI

1S/C3H9S.H2O/c1-4(2)3;/h1-3H3;1H2/q+1;/p-1

InChI key

MDTPTXSNPBAUHX-UHFFFAOYSA-M

一般描述

三甲基氢氧化硫 (TMSH) 是一种甲基化试剂。将碘化三甲基磺溶于甲醇和水溶剂中,用氧化银进一步处理即可制得。

应用

在一项使用热化学溶解-气相色谱-质谱法测定牛奶样品中脂肪酸的研究中,使用 TMSH 溶液作为衍生剂。

其他说明

该试剂用于甲基化羧酸类、醇类、硫醇类和 N-杂环化合物等亲核试剂;在 GC 中用于柱前酯化甘油酯的快速衍生化试剂

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 1

靶器官

Eyes,Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

51.8 °F - closed cup

闪点(°C)

11 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Sandra Meyer et al.
Journal of animal science and biotechnology, 11, 20-20 (2020-03-12)
The hypothesis was tested that insect meal (IM) as protein source influences intermediary metabolism of growing pigs. To test this, 30 male, 5-week-old crossbred pigs were randomly assigned to 3 groups of 10 pigs each with similar body weights (BW)
Lidia Lipińska et al.
Probiotics and antimicrobial proteins, 10(2), 186-200 (2017-11-08)
The antifungal activity of Lactobacillus pentosus ŁOCK 0979 depends both on the culture medium and on the fungal species. In the control medium, the strain exhibited limited antagonistic activity against indicator food-borne molds and yeasts. However, the supplementation of the
K. Yamauchi et al.
The Journal of Organic Chemistry, 44, 638-638 (1979)
Raimund Nagel et al.
Organic & biomolecular chemistry, 15(36), 7566-7571 (2017-09-01)
Bacteria can produce gibberellin plant hormones. While the bacterial biosynthetic pathway is similar to that of plants, the individual enzymes are very distantly related and arose via convergent evolution. The cytochromes P450 (CYPs) that catalyze the multi-step oxidation of the
Trimethylsulfonium hydroxide: a new methylating agent.
Yamauchi, Kiyoshi, Toshizumi Tanabe, and Masayoshi Kinoshita.
The Journal of Organic Chemistry, 44.4, 638- 639 (1979)

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