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应用
Trimethyl phosphite is an organophosphorus ester with flame retardant property. It is generally used as a ligand to form coordinate complexes with transition metals.
Some of its other applications include:
Some of its other applications include:
- For N-alkylation of amino-9,10-anthraquinones in imidazolium-based ionic liquids without the use of base and highly polar organic solvents.
- To synthesize dimethyl phenylphosphonate by reacting with phenyl radical generated by the thermal decomposition of phenylazotriphenylmethane (PAT).
- To synthesize aryl phosphonates via P-arylation reaction with silyl triflates.
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
82.4 °F - closed cup
闪点(°C)
28 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Free-radical chemistry of organophosphorus compounds. I. Reactions of phenyl radicals from phenylazotriphenylmethane with trimethyl phosphite.
Journal of the American Chemical Society, 94(22), 7710-7717 (1972)
Ionic liquids as novel and recyclable reaction media for N-alkylation of amino-9, 10-anthraquinones by trialkyl phosphites.
Tetrahedron Letters, 48(21), 3753-3756 (2007)
The chemistry of cyclopentadienyl-ruthenium and-osmium complexes. 1. The preparation and substitution reactions of (. eta. 4-cycloocta-1, 5-diene)(. eta. 5-cyclopentadienyl) haloruthenium (II) complexes. Versatile new synthetic precursors to open-face cyclopentadienylruthenium (II) chemistry.
Organometallics, 5(11), 2199-2205 (1986)
Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries.
Journal of Power Sources, 144(1), 170-175 (2005)
Mechanistic studies on halo-ligand substitution of five-coordinate trigonal-bipyramidal palladium (II) complexes of tris (2-(diphenylphosphino) ethyl) phosphine with trimethyl phosphite in chloroform at various temperatures and pressures.
Inorganic Chemistry, 35(18), 5163-5167 (1996)
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