92337
溴三甲基硅烷
purum, ≥97.0% (AT)
别名:
TMBS, 三甲基溴化硅, 三甲基溴硅烷
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关于此项目
线性分子式:
(CH3)3SiBr
化学文摘社编号:
分子量:
153.09
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-672-0
Beilstein/REAXYS Number:
1731135
MDL number:
产品名称
溴三甲基硅烷, purum, ≥97.0% (AT)
InChI key
IYYIVELXUANFED-UHFFFAOYSA-N
InChI
1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
SMILES string
C[Si](C)(C)Br
grade
purum
assay
≥97.0% (AT)
form
liquid
contains
silver wool as stabilizer
refractive index
n20/D 1.424 (lit.)
n20/D 1.424
bp
79 °C (lit.)
density
1.16 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
三甲基溴硅烷可作为衍生化试剂，用于通过气相色谱技术测定细胞培养基中的烷化溶血磷脂。
General description
三甲基溴硅烷可与Cl3共同用于催化烯丙基三甲基硅烷对各种醇的直接烯丙基化。
Other Notes
强效甲硅烷基化试剂；用于醚的裂解；以及膦酸和磷酸烷基酯的平稳裂解
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Gas chromatographic determination of alkyl lysophospholipids after solid-phase extraction from cell culture media
Coene J, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 612(1), 21-26 (1993)
S. Hanessian et al.
Tetrahedron Letters, 25, 2515-2515 (1984)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
J.L. Meek et al.
Journal of the American Chemical Society, 110, 2317-2317 (1988)
C. Flann et al.
Journal of the American Chemical Society, 109, 6097-6097 (1987)
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