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Merck
CN

89456

Supelco

4,4′,4″,4″-(卟啉-5,10,15,20-四)四(苯磺酸)

for spectrophotometric det. of transition metals, ≥95.0%

别名:

内消旋(4-磺酸苯基)卟吩

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About This Item

经验公式(希尔记法):
C44H30N4O12S4
CAS号:
分子量:
934.99
Beilstein:
4227566
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.21

质量水平

方案

≥95.0% (HPLC)
≥95.0%

表单

powder

质量

for spectrophotometric det. of transition metals

技术

UV/Vis spectroscopy: suitable

杂质

~9% water

SMILES字符串

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

应用

4,4′,4′′,4′′′-(卟啉-5,10,15,20-四基)四(苯磺酸)[四钠盐水合物,TPPS]已被用于制备Co–Al LDH/Fe(III)-TPPS薄膜修饰电极;用于证明Co(III)/Co(II)和铁(III)卟啉的可逆性氧化还原峰属性,该属性使其成为电子转移介质。

包装

无底玻璃瓶。内容物在插入式融锥内。

分析说明

最大吸收(甲醇溶液):412-416nm

其他说明

用于分光光度法测定超痕量过渡金属的试剂;用于毛细管区带电泳

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Lot/Batch Number

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访问文档库

Kalivarathan Divakar et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(1), 101-103 (2011-01-15)
Protein identification in polyacrylamide gel electrophoresis (PAGE) requires post-electrophoretic steps like fixing, staining and destaining of the gel, which are time-consuming and cumbersome. We have developed a method for direct visualization of protein bands in PAGE using tetrakis(4-sulfonato phenyl)porphyrin (TPPS)
Layer-by-layer assembly of porphyrin/layered double hydroxide ultrathin film and its electrocatalytic behavior for H 2 O 2.
Shao, Mingfei, et al.
Electrochemical Communications, 12.8, 1077-1080 (2010)
N Micali et al.
Nature chemistry, 4(3), 201-207 (2012-02-23)
Many essential biological molecules exist only in one of two possible mirror-image structures, either because they possess a chiral unit or through their structure (helices, for example, are intrinsically chiral), but so far the origin of this homochirality has not
E Collini
Physical chemistry chemical physics : PCCP, 14(11), 3725-3736 (2012-02-14)
In the search of new materials characterized by high two-photon absorption (TPA) efficiency, many efforts have been devoted to design chromophores with enhanced TPA responses progressively moving from linear chromophores such as dipoles and quadrupoles toward multimeric complex molecular architectures.
Kunio Kawamura et al.
Talanta, 84(5), 1318-1322 (2011-06-07)
A new type of flow injection analysis (FIA) system combined with an extremely high temperature reactor, namely hydrothermal flow injection analysis (HT-FIA), has been successfully constructed for the first time. Fundamental characteristics of HT-FIA system, such as limit temperature, pressure

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