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Merck
CN
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文件

89456

Supelco

4,4′,4″,4″-（卟啉-5,10,15,20-四）四（苯磺酸）

for spectrophotometric det. of transition metals, ≥95.0%

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别名:
内消旋(4-磺酸苯基)卟吩
经验公式（希尔记法）:
C44H30N4O12S4
CAS号:
35218-75-8
分子量:
934.99
Beilstein:
4227566
MDL编号:
MFCD00070632
UNSPSC代码:
12000000
PubChem化学物质编号:
329769738
NACRES:
NA.21

质量水平

100

检测方案

≥95.0% (HPLC)
≥95.0%

形式

powder

质量

for spectrophotometric det. of transition metals

技术

UV/Vis spectroscopy: suitable

杂质

~9% water

SMILES字符串

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

相关类别

应用

4,4′,4′′,4′′′-(卟啉-5,10,15,20-四基)四(苯磺酸)[四钠盐水合物，TPPS]已被用于制备Co–Al LDH/Fe(III)-TPPS薄膜修饰电极；用于证明Co(III)/Co(II)和铁(III)卟啉的可逆性氧化还原峰属性，该属性使其成为电子转移介质。

包装

无底玻璃瓶。内容物在插入式融锥内。

分析说明

最大吸收（甲醇溶液）：412-416nm

其他说明

用于分光光度法测定超痕量过渡金属的试剂；用于毛细管区带电泳

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Zsolt Valicsek et al.
Dalton transactions (Cambridge, England : 2003), 41(42), 13120-13131 (2012-09-25)
Lanthanum(III) ions form kinetically labile complexes with the 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin anion (H(2)TSPP(4-)), the compositions and formation constants of which significantly depend on the presence of potential axial ligands (at 0.01 M). Deviating from the chloride ion, acetate coordinating to the metal
Maria Angela Castriciano et al.
Chemical communications (Cambridge, England), 48(40), 4872-4874 (2012-04-14)
The kinetics of growth for chiral J-aggregates of H(4)TPPS(4) porphyrin have been investigated under different experimental conditions in the presence of tartaric acid. The observed rate constants and the anisotropy factor g show a defined dependence on the enantiomer used
H. Ishii, H. Tsuchiai
Analytical Sciences, 3, 229-229 (1987)
Chan Lee et al.
Toxicology, 283(2-3), 118-128 (2011-03-15)
Parkinson's disease (PD) is a progressive neurodegenerative movement disorder characterized by selective loss of dopaminergic neurons in the substantia nigra. 6-Hydroxydopamine (6-OHDA) is a catecholaminergic neurotoxin widely used to produce experimental models of PD and has been reported to cause
K. Kawamura et al.
Chemistry Letters (Jpn), 2217-2217 (1987)
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