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应用
2,2′-Thiodiethanol is used in the preparation of a wide range of gold complexes, which include Au(I) based catalysts such as chloro(triphenylphosphine)gold(I) [Au(PPh3)Cl], chloro(dimethyl sulfide)gold(I) [Au(SMe2)Cl] and chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) [IPrAuCl]. It can also be used to build calixarene frameworks.
警示用语:
Warning
危险声明
预防措施声明
危险分类
Eye Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Gold (I)?Catalyzed Intermolecular Cyclopropanation of Enynes with Alkenes: Trapping of Two Different Gold Carbenes.
Angewandte Chemie (International Edition in English), 118(36), 6175-6178 (2006)
A general synthesis for gold (I) complexes.
Inorg. Synth., 23, 191-194 (1985)
Networking of calixcrowns: From heteronuclear endo/exocyclic coordination polymers to a photoluminescence switch.
Journal of the American Chemical Society, 130(42), 13838-13839 (2008)
Binding and extraction of alkali and alkaline earth metals by nano-baskets of calix [4] arene-1, 2-crown-3.
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 73(1-4), 269-277 (2012)
Stereo-and regioselective gold-catalyzed hydroamination of internal alkynes with dialkylamines.
Journal of the American Chemical Society, 132(51), 18026-18029 (2010)
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