蒸汽密度
4.5 (vs air)
质量水平
蒸汽压
10 mmHg ( 57.7 °C)
等级
purum
检测方案
≥96.0% (NT)
形式
liquid
自燃温度
545 °F
expl. lim.
11.9 %
折射率
n20/D 1.404 (lit.)
n20/D 1.404
bp
167 °C (lit.)
mp
−43 °C (lit.)
溶解性
H2O: decomposes (when in contact with water)
密度
1.010 g/mL at 20 °C
1.015 g/mL at 25 °C (lit.)
SMILES字符串
CCC(=O)OC(=O)CC
InChI
1S/C6H10O3/c1-3-5(7)9-6(8)4-2/h3-4H2,1-2H3
InChI key
WYVAMUWZEOHJOQ-UHFFFAOYSA-N
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应用
Propionic anhydride can be used:
- As an esterifying reagent in the modification of cassava starch by acylation reaction.
- As a reactant along with anisole in the synthesis of 4-methoxypropiophenone using various solid acid catalysts via Friedel−Crafts acylation reaction.
- As a reagent in the synthesis of cyanohydrin esters by treating KCN with aldehyde in presence of bimetallic titanium(salen) complex catalyst.
其他说明
可能实行销售限制
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Modification of cassava starch by using propionic anhydride and properties of the starch-blended polyester polyurethane
Carbohydrate Polymers, 51(1), 17-24 (2003)
Synthetic and mechanistic studies on asymmetric cyanohydrin synthesis using a titanium (salen) bimetallic catalyst
Tetrahedron, 60(46), 10433-10447 (2004)
Journal of analytical toxicology, 33(8), 525-531 (2009-10-31)
Azide in human blood and plasma samples was derivatized with propionic anhydride in a headspace vial without prior sample preparation. The reaction proceeds quickly at room temperature to form propionyl azide. A portion of the headspace was assayed by gas
International journal of pharmaceutics, 337(1-2), 265-274 (2007-01-27)
Polyethylenimine (750 kDa) has been derivatized to influence the proton sponge mechanism and hydrophobic-hydrophilic balance. The polymer was acylated using acid anhydrides of varying carbon chain length, followed by cross-linking with PEG-bis-P to form compact nanoparticles. The chemical linkages in
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 826(1-2), 91-107 (2005-09-17)
N-Terminal isotope tagging (NIT) is an important proteomic tool for quantifying proteins in complex mixtures. Here we describe a modified version of the isotope-coded propionylation procedure of Zhang et al. [Zhang et al., Rapid Commun. Mass Spectom. 16 (2002) 2325]
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