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线性分子式:
CH3CH2CN
化学文摘社编号:
分子量:
55.08
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-464-4
Beilstein/REAXYS Number:
773680
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
InChI key
FVSKHRXBFJPNKK-UHFFFAOYSA-N
InChI
1S/C3H5N/c1-2-3-4/h2H2,1H3
SMILES string
CCC#N
grade
purum
assay
≥99.0% (GC)
form
liquid
Quality Level
bp
97 °C (lit.)
mp
−93 °C (lit.)
density
0.772 g/mL at 25 °C (lit.)
functional group
nitrile
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Application
- Propionitrile (PPN) is an effective solvent for catalytic asymmetric aldol reaction of a silyl enol ether with aldehydes in the presence of a chiral tin(II) Lewis acid catalyst.
- The co-solvent formed by mixing PPN with acetonitrile can be used to fabricate polymer gel electrolytes (PGEs) of dye-sensitized solar cells (DSSCs), which lead to enhanced stability of gel-state DSSCs.
- PPN can be used as a solvent for the Brønsted acid-catalyzed synthesis of N-alkyl cis-aziridines via [2+1] annulation of a diazo compound formed by the combination of an acetate and enolate. The process does not involve the use of metals or reagents and only atomic nitrogen as a co-product.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Stability improvement of gel-state dye-sensitized solar cells by utilization the co-solvent effect of propionitrile/acetonitrile and 3-methoxypropionitrile/acetonitrile with poly (acrylonitrile-co-vinyl acetate).
Venkatesan S, et al.
Journal of Power Sources, 274, 506-511 (2015)
The Br?nsted acid-catalyzed direct Aza-Darzens synthesis of N-alkyl cis-aziridines.
Williams A L and Johnston J N
Journal of the American Chemical Society, 126(6), 1612-1613 (2004)
Catalytic asymmetric aldol-type reaction using a chiral tin (II) Lewis acid.
Kobayashi S, et al.
Tetrahedron, 49(9), 1761-1772 (1993)
Sung Hee Joo et al.
Environmental science & technology, 41(4), 1288-1296 (2007-06-28)
The decreasing availability of pristine water supplies is prompting drinking water utilities to exploit waters impacted by wastewater effluents and agricultural runoff. As these waters feature elevated organic nitrogen concentrations, the pathways responsible for transformation of organic nitrogen into toxic
Sergey I Druzhinin et al.
The journal of physical chemistry. A, 110(47), 12760-12768 (2006-11-28)
Fast intramolecular charge transfer (ICT) accompanied by dual fluorescence from a locally excited (LE) and an ICT state taking place with N-phenylpyrrole (PP) in the solvent n-propyl cyanide (PrCN) is investigated as a function of temperature between 25 and -112
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