推荐产品
等级
analytical standard
质量水平
产品线
PESTANAL®
方案
≥98.0% (GC)
保质期
limited shelf life, expiry date on the label
应用
agriculture
包装形式
neat
储存温度
2-8°C
SMILES字符串
CN(C)CCCNC(OC([2H])([2H])C([2H])([2H])C([2H])([2H])[2H])=O
InChI
1S/C9H20N2O2/c1-4-8-13-9(12)10-6-5-7-11(2)3/h4-8H2,1-3H3,(H,10,12)/i1D3,4D2,8D2
InChI key
WZZLDXDUQPOXNW-GZAMCDGTSA-N
相关类别
一般描述
Propamocarb-(propyl-d7) is an isotope-labeled analog of systemic fungicide propamocarb, wherein propyl protons are substituted by deuterium.
应用
Propamocarb-(propyl-d7) may be used as a deuterated internal standard to quantify the pesticide analytes in foods of plant origin by two-dimensional liquid chromatography-tandem mass spectrometry (LC-MS/MS).
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
法律信息
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Quick method for the analysis of numerous highly polar pesticides in foods of plant origin via LC-MS/MS involving simultaneous extraction with methanol (QuPPe-method)
EU Reference Laboratie for Residue of Pesticides, 9, 1-60 (2015)
Simultaneous determination of pesticides, mycotoxins, tropane alkaloids, growth regulators, and pyrrolizidine alkaloids in oats and whole wheat grains after online clean-up via two-dimensional liquid chromatography tandem mass spectrometry
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 54(2), 98-111 (2019)
Simultaneous determination of pesticides, mycotoxins, and metabolites as well as other contaminants in cereals by LC-LC-MS/MS
Journal of Chromatography. B, Biomedical Applications, 1117(2), 86-102 (2019)
Dissipation kinetic studies of fenamidone and propamocarb in vegetables under greenhouse conditions using liquid and gas chromatography coupled to high-resolution mass spectrometry
EU Reference Laboratie for Residue of Pesticides, 226, 36-46 (2019)
Quick method for the analysis of numerous highly polar pesticides in foods of plant origin via LC-MS/MS involving simultaneous extraction with methanol (QuPPe-method)
Chemosphere, 1117(2), 86-102 (2019)
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