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Merck
CN

79590

Sigma-Aldrich

五氯化磷

purum p.a., ≥98.0% (AT)

别名:

氯化磷(V)

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About This Item

线性分子式:
PCl5
CAS号:
分子量:
208.24
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥98.0% (AT)
表单:
powder or crystals

蒸汽压

0.016 hPa ( 20 °C)

质量水平

等级

purum p.a.

方案

≥98.0% (AT)

表单

powder or crystals

杂质

≤0.005% total of sulfur (S)

pH值(酸碱度)

1 (5 g/L)

痕量阴离子

sulfate (SO42-): ≤50 mg/kg

痕量阳离子

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES字符串

ClP(Cl)(Cl)(Cl)Cl

InChI

1S/Cl5P/c1-6(2,3,4)5

InChI key

UHZYTMXLRWXGPK-UHFFFAOYSA-N

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一般描述

Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.

应用

Phosphorus pentachloride may be used in the synthesis of following compounds:
  • benzenesulfonyl chloride
  • malonic dinitrile
  • aromatic sulfonyl chlorides

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation

靶器官

Respiratory Tract

补充剂危害

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Infrared and Raman Spectra of Phosphorus Pentachloride.
Wilmshurst JK and Bernstein HJ.
J. Chem. Phys. , 27(3), 661-664 (1957)
Alec Lutzke et al.
ACS applied materials & interfaces, 9(3), 2104-2113 (2017-01-10)
Nitric oxide (NO) occurs naturally in mammalian biochemistry as a critical signaling molecule and exhibits antithrombotic, antibacterial, and wound-healing properties. NO-forming biodegradable polymers have been utilized in the development of antithrombotic or antibacterial materials for biointerfacial applications, including tissue engineering
Eagleson M.
Concise Encyclopedia Chemistry, 120-120 (1994)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Ino A and Murabayashi A.
Tetrahedron, 55(34), 10271-10282 (1999)
Travis Marshall-Roth et al.
Nature communications, 11(1), 5283-5283 (2020-10-21)
Iron- and nitrogen-doped carbon (Fe-N-C) materials are leading candidates to replace platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active site structures remain poorly understood. A leading postulate is that the iron-containing active sites exist

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