78780
异硫氰酸苯酯
for HPLC derivatization, the detection of alcohols and amines, ≥99.0%
别名:
PITC
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关于此项目
线性分子式:
C6H5NCS
化学文摘社编号:
分子量:
135.19
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-138-1
Beilstein/REAXYS Number:
471392
MDL number:
产品名称
异硫氰酸苯酯, for HPLC derivatization, the detection of alcohols and amines, ≥99.0%
form
liquid
assay
≥99.0%
InChI key
QKFJKGMPGYROCL-UHFFFAOYSA-N
InChI
1S/C7H5NS/c9-6-8-7-4-2-1-3-5-7/h1-5H
SMILES string
S=C=Nc1ccccc1
quality
for HPLC derivatization, the detection of alcohols and amines
refractive index
n20/D 1.649
n20/D 1.6515 (lit.)
bp
218 °C (lit.)
mp
−21 °C (lit.)
solubility
water: insoluble
density
1.13 g/mL at 20 °C
1.132 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
190.4 °F - closed cup
flash_point_c
88 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Determination of phenylisothiocyanate derivatives of amphetamine and its analogues in biological fluids by HPLC-APCI-MS or DAD.
Bogusz MJ, et al.
Journal of Analytical Toxicology, 21(1), 59-69 (1997)
Amin Zolali et al.
Combinatorial chemistry & high throughput screening, 17(7), 610-613 (2014-03-19)
An efficient, one-pot and three-component synthesis of biologically important heterocyclic compounds is described from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride at room temperature without the need to use any catalyst.
One-pot dehydrations using phenyl isothiocyanate.
Majetich G, et al.
Tetrahedron Letters, 56(23), 3326-3329 (2015)
Misako Aito-Inoue et al.
Journal of agricultural and food chemistry, 54(15), 5261-5266 (2006-07-20)
For the isolation and detection of food-derived peptides in blood, an approach based on the derivatization of peptides with phenyl isothiocyanate (PITC) was developed. This approach allows hydrophilic peptides to be resolved and specifically detected by reversed-phase (RP) HPLC. For
Fantao Meng et al.
Bioconjugate chemistry, 19(7), 1352-1360 (2008-06-25)
Successful and cost-effective PEGylation protocols require pure functionalized PEG reagents, which can be synthesized by simple and efficient procedures, exhibit high stability against hydrolysis, and maintain a level of reactivity with protein functional groups under mild reaction conditions. PEG-phenyl-isothiocyanate (PIT-PEG)
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