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Merck
CN

76778

丙烯酸甲酯

analytical standard

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关于此项目

线性分子式:
CH2=CHCOOCH3
化学文摘社编号:
96-33-3
分子量:
86.09
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
329767338
EC Number:
202-500-6
Beilstein/REAXYS Number:
605396
MDL number:
MFCD00008627

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InChI key

BAPJBEWLBFYGME-UHFFFAOYSA-N

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

SMILES string

COC(=O)C=C

grade

analytical standard

vapor density

3 (vs air)

vapor pressure

67.5 mmHg ( 20 °C)

assay

≥99.5% (GC)

autoignition temp.

874 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.0015% hydroquinone monomethyl ether as stabilizer

expl. lim.

14.5 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.402 (lit.), n20/D 1.403

bp

80 °C (lit.)

mp

−75 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

Quality Level

100

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相关类别

General description

该物质被列入欧盟法规10/2011关于拟与食品接触的塑料的许可列表中。

Application

在存在盐酸的热力条件下，丙烯酸甲酯可与1-丁醇发生酯交换反应，得到丙烯酸丁酯作为主要产物。
有关合适的仪器技术的更多信息，请参阅产品′的分析证书。想要获得更多支持，请联系技术服务部。

Other Notes

请在我们的在线平台NMR用请在我们的在线平台NMR用ChemisTwin®查找本产品的数字化标准物质。您可以利用ChemisTwin®上的数字化等效物质进行样品确认和化合物定量（采用数字化外标）。您可以查看该物质的NMR 谱，点击鼠标即可与您的样品在线比较。点击此处了解更多信息，并开始免费试用。

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

27.0 °F - closed cup

flash_point_c

-2.8 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN7390
BCCK2127
BCCF4354
BCBZ8471
BCBS5876V

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Organic Chemistry (2008)
Xin Liu et al.
Journal of hazardous materials, 175(1-3), 1014-1021 (2009-11-27)
Porous acrylonitrile (AN)/methyl acrylate (MA) copolymer beads were prepared by suspended emulsion polymerization. The cyano groups in AN/MA copolymer beads were converted to amidoxime (AO) groups by reaction with hydroxylamine hydrochloride (NH(2)OH.HCl) to remove metal ions in aqueous solution. The
Cláudio G L Junior et al.
Bioorganic chemistry, 38(6), 279-284 (2010-09-22)
Sixteen aromatic Morita-Baylis-Hillman adducts (MBHA) 1-16 were efficiently synthesized in a one step Morita-Baylis-Hillman reaction (MBHR) involving commercial aldehydes with methyl acrylate or acrylonitrile (81-100% yields) without the formation of side products on DABCO catalysis and at low temperature (0°C).
Nicky Chan et al.
Macromolecular rapid communications, 32(7), 604-609 (2011-03-26)
The use of copper tubing as both the reactor and as a catalyst source is demonstrated for continuous controlled radical polymerization of methyl acrylate at ambient temperature and at low solvent content of 30%. The high surface area provided by
Transformation of nickelalactones to methyl acrylate: on the way to a catalytic conversion of carbon dioxide.
S Y Tina Lee et al.
ChemSusChem, 4(9), 1275-1279 (2011-09-17)
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