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等级
analytical standard
质量水平
蒸汽密度
3 (vs air)
蒸汽压
67.5 mmHg ( 20 °C)
检测方案
≥99.5% (GC)
自燃温度
874 °F
保质期
limited shelf life, expiry date on the label
包含
~0.0015% hydroquinone monomethyl ether as stabilizer
expl. lim.
14.5 %
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.402 (lit.)
n20/D 1.403
bp
80 °C (lit.)
mp
−75 °C (lit.)
密度
0.956 g/mL at 25 °C (lit.)
应用
environmental
petroleum
格式
neat
SMILES字符串
COC(=O)C=C
InChI
1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3
InChI key
BAPJBEWLBFYGME-UHFFFAOYSA-N
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一般描述
该物质被列入欧盟法规10/2011关于拟与食品接触的塑料的许可列表中。
应用
在存在盐酸的热力条件下，丙烯酸甲酯可与1-丁醇发生酯交换反应，得到丙烯酸丁酯作为主要产物。
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警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
27.0 °F
闪点(°C)
-2.8 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Organic Chemistry (2008)
Jens Voepel et al.
Biomacromolecules, 12(1), 253-259 (2010-12-21)
A multifunctional macroinitiator for single-electron-transfer mediated living radical polymerization (SET-LRP) was designed from acetylated galactoglucomannan (AcGGM) by α-bromoisobutyric acid functionalization of the anomeric hydroxyl groups on the heteropolysaccharide backbone. This macroinitiator, with a degree of substitution of 0.15, was used
Mustafa Ciftci et al.
Chemical communications (Cambridge, England), 48(82), 10252-10254 (2012-09-13)
Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two
Daniel Duncan et al.
Dalton transactions (Cambridge, England : 2003), 40(9), 1998-2005 (2011-01-26)
A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between methyl acrylate and either aryl bromides or iodides, can be recovered intact by fluorous solid-phase extraction
Boris Neuwald et al.
Journal of the American Chemical Society, 135(3), 1026-1036 (2012-12-22)
Various phosphinesulfonato ligands and the corresponding palladium complexes [{((P^O)PdMeCl)-μ-M}(n)] ([{((X)1-Cl)-μ-M}(n)], (P^O) = κ(2)-P,O-Ar(2)PC(6)H(4)SO(2)O) with symmetric (Ar = 2-MeOC(6)H(4), 2-CF(3)C(6)H(4), 2,6-(MeO)(2)C(6)H(3), 2,6-(iPrO)(2)C(6)H(3), 2-(2',6'-(MeO)(2)C(6)H(3))C(6)H(4)) and asymmetric substituted phosphorus atoms (Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2'-(2,6-(MeO)(2)C(6)H(3))C(6)H(4); Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2-cHexOC(6)H(4)) were
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