76735
O -（2,3,4,5,6-五氟苄基）羟胺 盐酸盐
derivatization grade (GC derivatization), LiChropur™, ≥99.0% (AT)
别名:
PFBHA·HCl
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关于此项目
线性分子式:
C6F5CH2ONH2·HCl
化学文摘社编号:
分子量:
249.57
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
EC Number:
261-057-7
Beilstein/REAXYS Number:
4031190
MDL number:
Assay:
≥99.0% (AT)
Form:
solid
产品名称
O -（2,3,4,5,6-五氟苄基）羟胺 盐酸盐, derivatization grade (GC derivatization), LiChropur™, ≥99.0% (AT)
form
solid
InChI key
HVMVKNXIMUCYJA-UHFFFAOYSA-N
InChI
1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H
SMILES string
Cl.NOCc1c(F)c(F)c(F)c(F)c1F
grade
derivatization grade (GC derivatization)
assay
≥99.0% (AT)
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Alkylations
technique(s)
gas chromatography (GC): suitable
mp
212-218 °C
227 °C (subl.) (lit.)
solubility
H2O: 5%, clear
Quality Level
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Application
PFBHA.HCl 用于含羰基代谢物的衍生化，随后通过 GC-MS 进行分析。也可用于醛衍生化，然后使用 GC/MS 进行醛水解。
General description
O-（2,3,4,5,6-五氟苄基）羟胺盐酸盐（PFBHA.HCl）为衍生剂。
Other Notes
GC-ECD 分析羰基化合物（酮类固醇和碳水化合物）的灵敏的衍生化试剂
Packaging
无底玻璃瓶。内含物在插入的融合锥体内。
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Plasmalogen degradation by oxidative stress: production and disappearance of specific fatty aldehydes and fatty alpha-hydroxyaldehydes.
Stadelmann-Ingrand S
Free Radical Biology & Medicine, 31(10), 1263-1271 (2001)
Degradation of fluoranthene by Pasteurella sp. IFA and Mycobacterium sp. PYR-1:isolation and identification of metabolites.
Sepic E, Bricelj M, Leskovsek H.
Journal of Applied Microbiology, 85(4), 746-754 null
S Strassnig et al.
Journal of chromatography. A, 891(2), 267-273 (2000-10-24)
A method for the determination of carbonyl compounds, either directly from gaseous phase or following a volatilization from liquid or solid samples after trapping on Tenax TA is presented. Following solvent desorption, the carbonyls are derivatized using O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine. The reaction
Felix A Dingler et al.
Molecular cell, 80(6), 996-1012 (2020-11-05)
Reactive aldehydes arise as by-products of metabolism and are normally cleared by multiple families of enzymes. We find that mice lacking two aldehyde detoxifying enzymes, mitochondrial ALDH2 and cytoplasmic ADH5, have greatly shortened lifespans and develop leukemia. Hematopoiesis is disrupted
Christiane Collins et al.
Chemical research in toxicology, 16(12), 1560-1566 (2003-12-19)
Deoxyribose oxidation in DNA represents a biologically important facet of oxidative DNA damage that gives rise to protein-DNA cross-links and base adducts. Toward the goal of quantifying deoxyribose oxidation chemistry in cells, we report a method for the quantification of
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