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Merck
CN

76735

Supelco

O -(2,3,4,5,6-五氟苄基)羟胺 盐酸盐

for GC derivatization, LiChropur, ≥99.0% (AT)

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别名:
PFBHA·HCl
线性分子式:
C6F5CH2ONH2·HCl
CAS号:
分子量:
249.57
Beilstein:
4031190
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22

等级

for GC derivatization

质量水平

检测方案

≥99.0% (AT)

形式

solid

质量

LiChropur

反应适用性

reagent type: derivatization reagent
reaction type: Alkylations

技术

gas chromatography (GC): suitable

mp

212-218 °C
227 °C (subl.) (lit.)

溶解性

H2O: 5%, clear

SMILES字符串

Cl.NOCc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H

InChI key

HVMVKNXIMUCYJA-UHFFFAOYSA-N

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一般描述

O-(2,3,4,5,6-五氟苄基)羟胺盐酸盐(PFBHA.HCl)为衍生剂。

应用

PFBHA.HCl 用于含羰基代谢物的衍生化,随后通过 GC-MS 进行分析。也可用于醛衍生化,然后使用 GC/MS 进行醛水解。

包装

无底玻璃瓶。内含物在插入的融合锥体内。

其他说明

GC-ECD 分析羰基化合物(酮类固醇和碳水化合物)的灵敏的衍生化试剂

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Degradation of fluoranthene by Pasteurella sp. IFA and Mycobacterium sp. PYR-1:isolation and identification of metabolites.
Sepic E, Bricelj M, Leskovsek H.
Journal of Applied Microbiology, 85(4), 746-754 null
Plasmalogen degradation by oxidative stress: production and disappearance of specific fatty aldehydes and fatty alpha-hydroxyaldehydes.
Stadelmann-Ingrand S
Free Radical Biology & Medicine, 31(10), 1263-1271 (2001)
Y W Lin et al.
Applied occupational and environmental hygiene, 15(11), 855-862 (2000-11-04)
Ketones are the major positive interferences for an aldehyde dynamic air sampler that consists of 200-mg 20 percent (w/w) O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA) on Tenax TA contained in a Pyrex tube 7-mm OD, 5-mm ID, and 70-mm in length, that utilizes
Christiane Collins et al.
Chemical research in toxicology, 16(12), 1560-1566 (2003-12-19)
Deoxyribose oxidation in DNA represents a biologically important facet of oxidative DNA damage that gives rise to protein-DNA cross-links and base adducts. Toward the goal of quantifying deoxyribose oxidation chemistry in cells, we report a method for the quantification of
Julián Zapata et al.
Analytica chimica acta, 660(1-2), 197-205 (2010-01-28)
This work presents a comparative study of the analytical characteristics of two methods for the analysis of carbonyl compounds in wine, both based on the derivatization with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA). In the first method derivatives are formed in the solid

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