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Merck
CN

74731

1-十八硫醇

purum, ≥95.0% (GC)

别名:

Mercaptan C18, 十八硫醇, 正十八硫醇

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关于此项目

线性分子式:
CH3(CH2)17SH
化学文摘社编号:
分子量:
286.56
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
220-744-1
Beilstein/REAXYS Number:
1811934
MDL number:
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产品名称

1-十八硫醇, purum, ≥95.0% (GC)

InChI key

QJAOYSPHSNGHNC-UHFFFAOYSA-N

InChI

1S/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

SMILES string

CCCCCCCCCCCCCCCCCCS

grade

purum

assay

≥95.0% (GC)

form

solid

bp

204-210 °C/11 mmHg (lit.)

mp

30-33 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

Quality Level

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Analysis Note

熔化时可能含有沉淀

Application

ODT用于将硫醇化分子沉积到金基质的表面上,例如
  • 金石英晶体谐振器上的SAM。
  • 在原子力显微镜探针的尖端。
  • 电容式传感器。

General description

1-十八烷硫醇(ODT)是一种具有18碳烷基链的水溶性硫化合物,它与过渡金属(如金)形成强疏水性组装体,并在此类过渡金属表面形成自组装单层(SAM)。硫醇膜与金属电极表面共价键合时,显示出电致伸缩现象,导致电容变化。ODT SAM具有疏水表面,接触角为102oC。

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Polarization modulation Fourier transform infrared reflectance measurements of thin films and monolayers at metal surfaces utilizing real-time sampling electronics.
Barbara BJ, et al
Analytical Chemistry, 63(1), 55-60 (1991)
Reduced graphene oxide-templated photochemical synthesis and in situ assembly of Au nanodots to orderly patterned Au nanodot chains.
Xiao Huang et al.
Small (Weinheim an der Bergstrasse, Germany), 6(4), 513-516 (2010-01-16)
Ori Stein et al.
The journal of physical chemistry. B, 112(13), 3955-3962 (2008-03-08)
The interactions of water, carbon dioxide, and Xe with octadecanethiol (C(18)H(37)SH, ODT) self-assembled monolayers (SAMs) were studied under ultrahigh vacuum conditions employing temperature-programmed desorption and optical diffraction measurements. The ODT layer was grown on a 1 nm thick gold film
Diego Millo et al.
Colloids and surfaces. B, Biointerfaces, 81(1), 212-216 (2010-08-03)
Hybrid bilayer lipid membranes (HBMs) were built on roughened silver electrodes exhibiting surface-enhanced Raman scattering (SERS) activity. The HBM consisted of a first layer of octadecanethiol (ODT) directly bound to the electrode surface, on which a second layer of 1,2-diphytanoyl-sn-glycero-3-phosphocholine
Khalid S Salaita et al.
Nano letters, 6(11), 2493-2498 (2006-11-09)
Experiments that utilize structures generated by dip-pen nanolithography (DPN) as positive resists for fabricating nanohole arrays and lithographic masters are described. The technique takes advantage of the difference in desorption potentials for patterned structures made from 16-mercaptohexadecanoic acid (MHA) and

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