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Merck
CN

74332

Supelco

二嗪磷-二乙基-d10

PESTANAL®, analytical standard

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About This Item

经验公式(希尔记法):
C12D10H11N2O3PS
分子量:
314.41
MDL编号:
UNSPSC代码:
77101502
PubChem化学物质编号:
NACRES:
NA.24

等级

analytical standard

质量水平

同位素纯度

≥95 atom % D

产品线

PESTANAL®

方案

≥97.5% (GC)

保质期

limited shelf life, expiry date on the label

折射率

n20/D 1.4978 (lit.)

沸点

83-84 °C/0.002 mmHg (lit.)

应用

agriculture
environmental

包装形式

neat

质量偏移

M+10

储存温度

2-8°C

SMILES字符串

[2H]C([2H])([2H])C([2H])([2H])OP(=S)(Oc1cc(C)nc(n1)C(C)C)OC([2H])([2H])C([2H])([2H])[2H]

InChI

1S/C12H21N2O3PS/c1-6-15-18(19,16-7-2)17-11-8-10(5)13-12(14-11)9(3)4/h8-9H,6-7H2,1-5H3/i1D3,2D3,6D2,7D2

InChI key

FHIVAFMUCKRCQO-HXOHQZFQSA-N

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一般描述

Diazinon-(diethyl-d10) is an isotope labeled analog of the organophosphate pesticide diazinon, wherein the diethoxy protons are replaced by deuterium.

应用

Diazinon-(diethyl-d10) may be used as an internal standard for the determination of diazinon in soybeans and Daphnia magna by various chromatography techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

法律信息

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

235.0 °F - closed cup

闪点(°C)

112.8 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Accurate determination of selected pesticides in soya beans by liquid chromatography coupled to isotope dilution mass spectrometry
Perez JFH, et al.
Talanta, 137(2), 120-129 (2015)
Gas chromatography-isotope dilution mass spectrometry method validation for target pesticides in soybeans
Huertas-Perez, JF, et al.
Food Additives & Contaminants. Part A, Chemistry, Analysis, Control, Exposure & Risk Assessment, 36(1), 96-108 (2019)
In vitro rat hepatic and intestinal metabolism of the organophosphate pesticides chlorpyrifos and diazinon
Poet TS, et al.
Toxicological Sciences, 72(2), 193-200 (2003)
Toxicokinetic Model Describing Bioconcentration and Biotransformation of Diazinon in Daphnia magna
Preuss TG, et al.
Environmental Science & Technology, 45(1), 4995-5002 (2011)

商品

Pesticide analysis, SPME Fiber, supelco spme fiber, direct immersion spme, pesticide analysis methods, pesticide analysis by gc-ms, DI-SPME, overcoated SPME, overcoated fibers, soy milk analysis

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